石油化工高等学校学报2024，Vol.37Issue(2)：50-57,8.DOI:10.12422/j.issn.1006-396X.2024.02.007
Cu-Mn-Al三元尖晶石催化甲醇重整反应特性
Characteristics of Methanol Steam Reforming Catalyzed by Cu-Mn-Al Ternary Spinel
摘要
Abstract
Cu0.7Mn0.3Al2.5 ternary solid solution spinel catalysts were prepared by ball milling method using copper nitrate as the copper source,proposed thin alumina as the aluminium source,citric acid as the additive,and manganese acetate as the third component to partially replace copper.With the help of characterisation techniques such as XRD,BET,H2-TPR and XPS,the crystalline phase structure,weaving properties,reducing properties and surface cation states and distributions of Cu0.7Mn0.3Al2.5 were investigated.The catalytic performance of Cu0.7Mn0.3Al2.5 in methanol steam reforming(MSR)for hydrogen production with a sustained release feature was scrutinized,and a comparison was made with CuAl2.5 binary spinel and Cu0.7Zn0.3Al2.5 ternary spinel catalysts.The results showed that compared with CuAl2.5 and Cu0.7Zn0.3Al2.5,the Cu0.7Mn0.3Al2.5 exhibited the maximum contraction of the unit cell,resulting in a smaller unit cell constant.The catalyst had smaller crystalline size and higher specific surface area.The catalyst showed an aluminium-rich state,but with a higher percentage of Cu in the surface spinel phase,which made the reduction under H2 atmosphere more difficult,and exhibited a better slow-release catalytic performance in MSR hydrogen production.Under the conditions of a reaction temperature of 265 °C,n(H2O)/n(CH3OH)=2,and mass flow rate of 2.25 h-1,a stable conversion rate of 84%was achieved for 40 hours.The study provided valuable data reference for the development of efficient copper-based sustained-release catalysts.关键词
缓释催化/甲醇重整/尖晶石/球磨法Key words
Sustained release/Methanol steam reforming/Spinel/Ball-milling method分类
化学工程引用本文复制引用
吕昌赫,吴殿卿,张楷文,于东北,张财顺,韩蛟,高志贤..Cu-Mn-Al三元尖晶石催化甲醇重整反应特性[J].石油化工高等学校学报,2024,37(2):50-57,8.基金项目
国家自然科学基金项目(22379059) （22379059）
辽宁省应用基础研究计划项目(2023JH2/101300224) （2023JH2/101300224）
辽宁省教育厅服务地方项目(LJKFZ20220201). （LJKFZ20220201）
