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酰基季铵盐脱硅捕收剂的合成与应用

陈友顺 徐廷航 张逸 龙秉文 邓伏礼 戴亚芬 丁一刚

武汉工程大学学报2024,Vol.46Issue(2):119-124,6.
武汉工程大学学报2024,Vol.46Issue(2):119-124,6.DOI:10.19843/j.cnki.CN42-1779/TQ.202311018

酰基季铵盐脱硅捕收剂的合成与应用

Synthesis and application of acyl quaternary ammonium salt desilication collector

陈友顺 1徐廷航 1张逸 1龙秉文 1邓伏礼 1戴亚芬 1丁一刚1

作者信息

  • 1. 武汉工程大学化工与制药学院,绿色化工过程教育部重点实验室(武汉工程大学),湖北 武汉 430205
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摘要

Abstract

Using dodecanoyl chloride,dimethylaminopropylamine,and bromoethane as starting materials,a highly efficient acyl quaternary ammonium salt,i.e.collector XN-12 that can selectively float and remove silica under under acidic pulp conditions was synthesized.Flotation results show that in single quartz mineral flotation experiments,XN-12 has good flotation performance on quartz under conditions of mineral slurry with pH>5;when directly subjected to single reverse flotation desilication using XN-12 for high-silica phosphate ore,under acidic mineral slurry conditions at pH = 5.6,with a dosage of 5.0 kg/t of sodium tripolyphosphate depressant and 1.2 kg/t of XN-12,the obtained phosphorus concentrate had good indicators of P2O5 grade 30.31%,recovery rate 81.60%,SiO2 grade 7.26%,and desilication rate 69.12%.

关键词

磷矿/脱硅/季铵盐/合成/反浮选

Key words

phosphate rock/desilication/quaternary ammonium salt/synthesis/reverse flotation

分类

矿业与冶金

引用本文复制引用

陈友顺,徐廷航,张逸,龙秉文,邓伏礼,戴亚芬,丁一刚..酰基季铵盐脱硅捕收剂的合成与应用[J].武汉工程大学学报,2024,46(2):119-124,6.

基金项目

湖北省技术创新专项(2020BED030) (2020BED030)

武汉工程大学学报

1674-2869

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