物理学进展2024，Vol.44Issue(2)：73-95,23.DOI:10.13725/j.cnki.pip.2024.02.002
卤化物钙钛矿金属位铋离子掺杂的调控研究进展
Research Progress on the Regulation of Metal-Site Bismuth Doping in Halide Perovskites
摘要
Abstract
High-performance metal halide perovskites solar cells are currently in the transi-tion from laboratory research to industrial production and have demonstrated their immeasur-able application value in the future global energy field.To achieve high-performance metal halide perovskite solar cells,the perovskite materials used as active working layers have undergone a decade-long optimization process resulting in significant progress.Focusing on the modulation research of metal-site bismuth ion doping in high-performance halide perovskites,this paper provides a systematic summary of the development and conventional preparation process of halide perovskites thin films.Researches have shown that ternary cationic perovskites can inhibit the formation of the yellow phase,change grain size,and improve stability,etc.,and become the primary choice for future high-performance perovskite photoelectric devices.The following section discusses the Bi3+ doped perovskite system.The special electronic structure and non-toxic chemical properties of Bi3+ improve the stability of perovskites and regulate the photoelectric properties,resulting in the preparation of high-performance solar cells.Finally,based on the current research status of halide perovskites solar cells,we foresee that the bis-muth ion doping strategy and ternary mixed cation perovskites can be combined in the future device optimization processes.Additionally,several potential research directions for achieving high-performance metal halide chalcogenide solar cells are highlighted.关键词
钙钛矿/铋离子/掺杂/太阳能电池/光电性能Key words
perovskites/bismuth/doping/solar cells/photoelectric properties分类
信息技术与安全科学引用本文复制引用
黄小芮,孙悦,贺圣荣,邢军..卤化物钙钛矿金属位铋离子掺杂的调控研究进展[J].物理学进展,2024,44(2):73-95,23.基金项目
感谢新疆维吾尔自治区自然科学基金青年基金(2022D01C66),新疆维吾尔族自治区研究生创新项目(XJ2023G084),新疆维吾尔自治区天山创新团队项目(2023D14001),新疆维吾尔自治区天池博士基金项目(TCBS202138),新疆大学博士科研启动基金项目(202102120012)资助. （2022D01C66）
