用于电催化合成过氧化氢的碳电极综述OA北大核心CSTPCD

Electrocatalytic oxygen reduction by a 2e pathway enables the instantaneous synthesis of H2O2,a process that is far superior to the conventional anthraquinone process.In recent years,the electrocatalytic synthesis of H2O2 using carbon electrodes has attracted more and more attention because of its excellent catalytic performance and superior stability.The relationship between ma-terial modification,wettability and the rate of H2O2 synthesis and service life is considered together with the three-phase interface.The structure of the carbon electrodes and the principles of electrocatalytic H2O2 synthesis are first introduced,and four major cata-lysts are reviewed,namely,monolithic carbon materials,metal-free catalysts,noble metal catalysts and non-precious metal catalysts.The effects of the metal anode and the electrolyte on the three-phase interface are described.The relationship between carbon elec-trode wettability and the three-phase interface is described,pointing out that modification focusing on improving the selectivity of the 2e pathway can also impact electrode wettability.In addition,the relationship between the design of the components in the electro-chemical system and their effect on the efficiency of H2O2 synthesis is discussed for carbon electrodes.Finally,we present our ana-lysis of the current problems in the electrocatalytic synthesis of H2O2 for carbon electrodes and future research directions.