GH4169合金低温渗硼层结构与耐磨性能研究OA
Study on the Microstructure and Tribological Properties of a Low-temperature Boronizing Layer on GH4169 Alloy
GH4169 合金因具有良好的高温强度及耐腐蚀性等,在航空航天领域应用广泛,但其也存在表面硬度低、耐磨性差的问题.固相渗硼是提高GH4169 合金耐磨性能的有效手段,但常用渗硼工艺普遍采用 900℃以上高温,这会破坏合金时效处理所得到的析出相结构.本实验将GH4169 合金热处理时效过程与渗硼过程相统一,通过引入ZrO2 作为新型催渗剂获得了厚度约 8.2 μm的致密渗硼层.分析发现渗硼层由Cr5B3、Cr2B、Ni2B和FexNi23-xB6 复合相组成,表面硬度高达 2 622.9 HV0.1,并在与氮化硅球对磨时呈现出极低的磨损率值,即 8.5×10-6 mm3/(N·m).
GH4169 is a classical superalloy material with good high-temperature strength,fatigue strength and corrosion resistance but also suffers from low surface hardness and poor wear resistance.Boronising treatment is one of the most effective approaches for improving the surface properties of GH4169 alloys.However,due to the high boriding temperature(i.e.,above 900℃),the precipitated phase structure obtained during the aging treatment is destroyed,which affects the mechanical performance.In the present study,a GH4169 alloy was successfully boronised under ageing conditions,and a dense boride layer with a thickness of~8.2 μm was obtained.The boride layer is composed of mixed Cr5B3,Cr2B,Ni2B and FexNi23-xB6 phases and has an ultrahigh hardness of 2 622.9 HV0.1.Additionally,ultralow wear rates(8.5×10-6 mm3/N·m)are obtained when friction occurs against Si3N4 balls.The findings of the present study will be beneficial for the practical use of boronising treatment in nickel-based superalloys.
官磊;邵孟雪;胡晨阳;陈树群
中国航发北京航空材料研究院,北京 100095北京工业大学材料科学与工程学院,北京 100124
金属材料
高温合金低温硼化催渗剂磨损机制
nickel-based superalloylow temperature boronisingactivatorwear mechanism
《铸造技术》 2024 (004)
349-355 / 7
北京市科协青年人才托举工程(BYESS2023059)
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