化工学报2024，Vol.75Issue(3)：1052-1064,13.DOI:10.11949/0438-1157.20240133
化工过程中的电子传递、质子传递和分子传递
Electron transfer,proton transfer and molecule transfer in chemical processes
摘要
Abstract
The concept of"green chemistry"and"sustainable development"as well as the mission of"carbon peaking and carbon neutrality"(dual carbon)have been put forward successively.Thereby,chemical industry has stepped into a new era of green,high-end and intelligent.In reaction-involved chemical processes,there exists very famous"momentum-heat-mass transfer"(classical"Three Transfers")theory,which takes reaction kinetics as the core and the momentum transfer,heat transfer and mass transfer as the fundamental basis,correlating the intensification principles of mass/energy transfer and chemical reaction.The classical"Three Transfers"is of important and far-reaching significance for the development of chemical industry.In recent years,due to the introduction of clean energy,such as solar energy and electric energy as well as new disciplines such as green biomanufacturing and photo-/electro-chemical engineering into the chemical processes,three types of transfer phenomena represented by electron transfer,proton transfer and molecule transfer have attracted tremendous attentions,injecting new vitality into classical"Three Transfers".In this context,we attempt to extensively analyze and introduce these three types of transfer phenomena.The strategies for individual or synergistic intensification of electron transfer,proton transfer and molecule transfer are summarized based on the characteristics of different chemical reactions,aiming to acquire a highly matched mass transfer-reaction processes and significantly improved chemical reaction efficiency.关键词
电子传递/质子传递/分子传递/化工过程/化学反应/生物催化/太阳能Key words
electron transfer/proton transfer/molecule transfer/chemical process/chemical reaction/biocatalysis/solar energy分类
化学化工引用本文复制引用
李诗浩,吴振华,赵展烽,吴洪,杨冬,石家福,姜忠义..化工过程中的电子传递、质子传递和分子传递[J].化工学报,2024,75(3):1052-1064,13.基金项目
国家重点研发计划项目(2022YFC2105903) （2022YFC2105903）
国家自然科学基金优秀青年科学基金项目(22122809) （22122809）
国家自然科学基金项目(21621004) （21621004）
生化工程国家重点实验室开放基金项目(2020KF-06) （2020KF-06）
物质绿色创造与制造海河实验室、高等学校学科创新引智计划2.0(BP0618007) （BP0618007）
