日用化学工业（中英文）2024，Vol.54Issue(5)：507-513,7.DOI:10.3969/j.issn.2097-2806.2024.05.002
一种含偶氮苯的二肽表面活性剂的合成及自组装行为
Synthesis and self-assembly of an azobenzene-containing dipeptide surfactant
摘要
Abstract
A glycylglycine-derived surfactant containing an azobenzene moiety as terminal(Azo-C6-GG)was synthesized.Azo-C6-GG self-assembled into vesicles driven by several non-covalent interactions.The trans-azobenzene transformed to cis-azobenzene after the irradiation of UV light,and vesicles were still formed in this cis-Azo-C6-GG system.A supra-amphiphile(Azo-C6-GG@α-CD)was formed after the addition of α-cyclodextrin(α-CD),which formed vesicles in aqueous solution.The azobenzene group was embedded into the cavity of α-CD,and meanwhile,the CD ring shuttled between the alkyl chain and the azobenzene group.After the UV light irradiation,the alkyl chain was embedded into the cavity of α-CD.The Azo-C6-GG@α-CD complexes were found to self-assemble into vesicles both before and after the UV light irradiation.关键词
偶氮苯/环糊精/光照/囊泡/自组装Key words
azobenzene/cyclodextrin/light irradiation/vesicle/self-assembly分类
化学化工引用本文复制引用
赵淋淋,焦宇恬,赵莉,王策,徐宝财..一种含偶氮苯的二肽表面活性剂的合成及自组装行为[J].日用化学工业（中英文）,2024,54(5):507-513,7.基金项目
国家自然科学基金资助项目(22008002) （22008002）
北京市属事业单位青年拔尖人才培养项目(BPHR2203049) （BPHR2203049）
