材料科学与工程学报2024，Vol.42Issue(2)：311-319,9.DOI:10.14136/j.cnki.issn1673-2812.2024.02.020
Li7La3Zr2O12固态电解质负极界面研究进展
Progress of Li7La3Zr2O12 Solid Electrolyte Anode Interface
摘要
Abstract
The garnet-type solid electrolyte Li7La3Zr2O12(LLZO)has a wide electrochemical window of 5 V,and among current solid electrolyte systems,it has a good match with the metal lithium anode,which makes it promising to develop into the next-generation high-energy battery.However,the problem of contact stability between LLZO and the electrode greatly limits its practical application.In this paper,we first analyze the stability of the LLZO/Li anode interface from three aspects:the properties of lithium metal anode,the properties of LLZO solid electrolyte,the interfacial contact of LLZO and lithium metal anode.Then we also expound the root cause of interface stability,summarize the corresponding optimization method.Finally,we put forward the problems that should be paid attention to the development of the LLZO/Li anode interface as a reference to the practical application of all-solid-state lithium-ion batteries.关键词
LLZO负极界面改性/金属锂负极/全固态锂电池/LLZO/Li界面微观机理Key words
LLZO anode interface modification/Metallic lithium anode/All-solid-state lithium battery/LLZO/Li interface micromechanism分类
通用工业技术引用本文复制引用
吴非,刘涛..Li7La3Zr2O12固态电解质负极界面研究进展[J].材料科学与工程学报,2024,42(2):311-319,9.基金项目
国家自然科学基金资助项目(51974072) （51974072）
中央高校基本科研业务费专项资金资助项目(N2125028) （N2125028）
