电化学（中英文）2024，Vol.30Issue(2)：35-45,11.DOI:10.13208/j.electrochem.2303241
电极过程动力学反应速率常数测量的若干方法
Measurements of Rate Constant for Electrode Reactions
摘要
Abstract
Standard electron-transfer rate constant is one of the intrinsic properties for an electrochemical reaction, which is significant in the study of electrode kinetics. It is a key criterion for one to clarify the mechanism and pathway of a specific electrochemical reaction, and to screening and design the electrocatalysts and battery materials. Herein, we will introduce the measuring methods of rate constant for electrode reactions, including polarization curve, rotating disk electrode, ultramicroelectrode, scanning electrochemical microscopy, electrochemical impedance spectroscopy, current step, potential step and cyclic voltammetry, etc., to provide a guide to investigate electrode kinetics for graduate students and researchers in the related fields.关键词
反应速率常数/传质速率/稳态方法/暂态方法Key words
Rate constant/Mass-transfer coefficient/Stationary techniques/Transient techniques引用本文复制引用
韩联欢,郭佳瑶,崔苗苗..电极过程动力学反应速率常数测量的若干方法[J].电化学（中英文）,2024,30(2):35-45,11.基金项目
国家自然科学基金(No.22202166,No.21827802,No.22132003和No.22021001)和中央高校基本科研业务费专项资金(No.20720230076)资助 （No.22202166,No.21827802,No.22132003和No.22021001）
