电化学(中英文)2024,Vol.30Issue(4):1-5,5.DOI:10.13208/j.electrochem.2313001
电催化活性亚甲基化合物的环丙烷化反应
Electrocatalytic Cyclopropanation of Active Methylene Compounds
摘要
Abstract
The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates,natural products,and pharmaceuticals.Herein,we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes.This electrochemical process requires no chemical oxi-dants,allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.关键词
电化学/有机电合成/催化剂/环丙烷/烯烃Key words
Electrochemistry/Cyclopropane/Catalyst/Alkene/Organic electrosynthesis引用本文复制引用
揭亮华,徐海超..电催化活性亚甲基化合物的环丙烷化反应[J].电化学(中英文),2024,30(4):1-5,5.基金项目
This work was supported by the National Natu-ral Science Foundation of China(No.22225101)and Fundamental Research Funds for the Central Universities(No.20720210003). (No.22225101)