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电催化活性亚甲基化合物的环丙烷化反应

揭亮华 徐海超

电化学(中英文)2024,Vol.30Issue(4):1-5,5.
电化学(中英文)2024,Vol.30Issue(4):1-5,5.DOI:10.13208/j.electrochem.2313001

电催化活性亚甲基化合物的环丙烷化反应

Electrocatalytic Cyclopropanation of Active Methylene Compounds

揭亮华 1徐海超1

作者信息

  • 1. 固体表面物理化学国家重点实验室,福建省化学生物学重点实验室,厦门大学化学与化工学院,福建厦门 361005
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摘要

Abstract

The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates,natural products,and pharmaceuticals.Herein,we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes.This electrochemical process requires no chemical oxi-dants,allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.

关键词

电化学/有机电合成/催化剂/环丙烷/烯烃

Key words

Electrochemistry/Cyclopropane/Catalyst/Alkene/Organic electrosynthesis

引用本文复制引用

揭亮华,徐海超..电催化活性亚甲基化合物的环丙烷化反应[J].电化学(中英文),2024,30(4):1-5,5.

基金项目

This work was supported by the National Natu-ral Science Foundation of China(No.22225101)and Fundamental Research Funds for the Central Universities(No.20720210003). (No.22225101)

电化学(中英文)

OA北大核心CSTPCD

1006-3471

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