大学化学2024，Vol.39Issue(4)：107-113,7.DOI:10.3866/PKU.DXHX202310117
乙酸乙酯皂化反应速率常数的测定实验改进和拓展
Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate
摘要
Abstract
This paper focuses on the improvement and expansion of the experiment"Determination of the Rate Constant of Ethyl Acetate Saponification Reaction"in existing Physical Chemistry Experiment textbooks.Firstly,the saponification reaction vessel is replaced with a jacket beaker to ensure the uniform concentration and constant temperature of the solution during the experiment through constant temperature water circulation and magnetic stirring.Secondly,a certain volume of 0.01 mol·L-1 sodium hydroxide solution is taken and the conductivity value is measured after reaching a constant temperature,denoted as κ0.Then,an equal molar amount of ethyl acetate is added to the reactor using a micro sampler while simultaneously recording the conductivity values at different times,denoted as κt.Thirdly,the influence of electrode constant is eliminated through data normalization,providing clear physical quantities and intuitive experimental phenomena.The improved experimental procedure reduces steps and improves the accuracy of data measurement,allowing for the measurement of the rate constant of rapid saponification reactions under high temperature conditions.Within limited class time,students can obtain the apparent activation energy and pre-exponential factor through division of labor,collaboration,and data sharing.关键词
物理化学实验/皂化反应/速率常数/表观活化能/指前因子Key words
Physical chemistry experiment/Saponification reaction/Rate constant/Apparent activation energy/Pre-exponential factor分类
社会科学引用本文复制引用
祝淑颖,吴舒婷,郑欧..乙酸乙酯皂化反应速率常数的测定实验改进和拓展[J].大学化学,2024,39(4):107-113,7.基金项目
2022年福建省本科高校教育教学研究项目(FBJG20220268) （FBJG20220268）
