高锰酸盐指数测定仪在多水源供水系统中的应用OACSTPCD
Application of Permanganate Index Tester in Multi-Source Water Supply System
目前,国内大多数供水监测实验室采用国标滴定法测定高锰酸盐指数,操作步骤繁琐,易产生手工误差,而仪器检测方法的开发及应用研究仍不系统、不全面.文中通过对高锰酸盐指数智能测定仪的加热时间、加热功率、温度补偿、滴定区域温度等条件参数进行试验筛选,建立一种适用于测定生活饮用水、海水淡化水及水源水中高锰酸盐指数的仪器检测方法,并探明其受海拔条件影响规律和原因.研究运用该仪器方法测定低、中、高3 个浓度的纯水和实际水样质控样品,试验结果表明其相对标准偏差为 0.35%~4.55%,回收率为 87.9%~104.6%,均优于国标滴定法.此外将该方法应用于实际样品的高锰酸盐指数测定,其与国标滴定法的相对偏差为 0.60%~3.39%,同时开展两批次 50 个实际水样连续测定试验,标准偏差分别为3.37%和 3.77%.其检出限、测定下限、精密度、准确度、稳定性均能满足对生活饮用水、海水淡化水、水源水等多类水样的高锰酸盐指数连续检测的要求,具有广阔的实际应用前景.
At present,most domestic water supply monitoring laboratories use the national standard titration method to measure the permanganate index,which is cumbersome and prone to manual errors.However,the development and application research of instrument detection methods are still not systematic and comprehensive.This paper established an instrument detection method suitable for measuring the permanganate index in drinking water,seawater desalination water,and source water through experimental screening of the heating time,heating power,temperature compensation,titration zone temperature and other conditional parameters of the intelligent permanganate index measuring instrument,and explores the laws and reasons affected by altitude conditions.The study used this instrument method to determine pure water with low,medium,and high concentrations and actual water quality control samples.The experimental results showed that the relative standard deviation was 0.35%~4.55%,and the recovery rate was 87.9%~104.6%,all of which were better than the national standard titration method.In addition,this method was applied to the determination of permanganate index in actual samples,and its relative deviation from the national standard titration method was 0.60%~3.39%.Two batches of 50 actual water samples were tested continuously,with standard deviations of 3.37%and 3.77%,respectively.Its detection limit,lower detection limit,precision,accuracy,and stability can meet the requirements for continuous detection of permanganate index in multiple types of water samples such as drinking water,desalinated seawater,and raw water,and has broad practical application prospects.
韩宛汝;孙扬;谢文利;杨慧贤;王春虎;孙贤鹏
青岛水务集团有限公司,山东青岛 266071||青岛市海润自来水集团有限公司,山东青岛 266071||青岛海诚水质监测技术有限公司,国家城市供水水质监测网青岛监测站,山东青岛 266034青岛水务集团有限公司,山东青岛 266071青岛水务集团有限公司,山东青岛 266071||青岛市海润自来水集团有限公司,山东青岛 266071
土木建筑
高锰酸盐指数智能测定仪法国标滴定法多水源供水海水淡化水
permanganate indexintelligent instrument methodnational standard titration methodmulti-source water supply desalinated seawater
《净水技术》 2024 (005)
204-213 / 10
国家重点研发计划(2022YFF0609104)
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