| 注册
首页|期刊导航|石油化工|高流动性刚韧平衡聚丙烯的开发及性能

高流动性刚韧平衡聚丙烯的开发及性能

张闽

石油化工2024,Vol.53Issue(5):718-722,5.
石油化工2024,Vol.53Issue(5):718-722,5.DOI:10.3969/j.issn.1000-8144.2024.05.014

高流动性刚韧平衡聚丙烯的开发及性能

Development and performance of polypropylene with high flowability and stiffness-toughness balance

张闽1

作者信息

  • 1. 中韩(武汉)石油化工有限公司,湖北 武汉 430082
  • 折叠

摘要

Abstract

Polypropylene product M30RH with high flowability and stiffness-toughness balance was prepared by hydrogen adjustment method using HR catalyst with high hydrogen sensibility and high stereoregularity,combined with efficient nucleating agent technology in a 300 kt/a ST loop reactor.The structure and properties of M30RH were analyzed with melt flow rate(MFR)test,IR,SEM,DSC,and POM.The results show that M30RH has MFR(10 min)of 30.7 g,rubber phase content of 19.7%(w),room temperature notched charpy impact strength of 9.3 kJ/m2,bending modulus of 1 304 MPa,and odor level of 3.9.Compared with commercially available products,the ethylene units of M30RH tend to distribute in the rubber phase and M30RH has a better balance between stiffness and toughness.The crystallization performance of M30RH is basically the same as that of commercially available products,which improves rigidity and processing efficiency while maintaining toughness.

关键词

聚丙烯/高流动性/刚韧平衡/HR催化剂

Key words

polypropylene/high flow/stiffness-toughness balance/HR catalyst

分类

化学化工

引用本文复制引用

张闽..高流动性刚韧平衡聚丙烯的开发及性能[J].石油化工,2024,53(5):718-722,5.

石油化工

OA北大核心CSTPCD

1000-8144

访问量0
|
下载量0
段落导航相关论文