化学链燃烧中载氧体磨损及抗磨损方法研究进展OA北大核心CSTPCD
Research progress on oxygen carrier attrition and anti-attrition methods in chemical looping combustion
大规模使用化石燃料导致CO2大量排放,由此引发的全球气候问题受到广泛关注.化学链燃烧采用循环载氧体为燃料提供活性氧,改进了传统燃烧方式,避免了N2对烟气的稀释,降低了CO2的捕集成本,具有CO2内分离的优点,在CO2捕集领域具有较大发展潜力.载氧体是化学链燃烧技术的核心,具有传递热量和释放晶格氧的双重作用,但面临磨损率大和寿命较短的问题,严重影响化学链燃烧技术的经济性.综述了载氧体磨损的表观现象和内在机理,发现化学磨损是载氧体磨损的主要因素;总结了评估和预测载氧体磨损的方法,以及提高载氧体耐磨性的方法,并对未来载氧体的研究方向进行了展望.
The large-scale use of fossil fuels has led to excessive CO2 emissions,and the resulting global climate problems have received widespread attention.Chemical looping combustion improves the traditional combustion method by using a circulating oxygen carrier to provide active oxygen to the fuel,avoiding the dilution of N2 to the flue gas,reducing the cost of CO2 capture and has the advantage of internal separation of CO2,which has a great potential for development in the field of CO2 capture.Oxygen carrier is the core of chemical looping combustion technology,which plays the dual role of transferring heat and releasing lattice oxygen,but the oxygen carrier faces the problems of large attrition rate and short lifetime,which seriously affect the economy of chemical looping combustion technology.The apparent phenomena and intrinsic mechanism of oxygen carrier attrition were reviewed,and chemical attrition is found to be the main factor of oxygen carrier attrition.The methods of assessing and predicting the attrition of oxygen carrier as well as the methods of improving the abrasion resistance of oxygen carrier were summarized,and the future research of oxygen carrier was also prospected.
朱丹;刘方;宋晨;杨丽
中国矿业大学 低碳能源与动力工程学院,江苏 徐州 221116
化学工程
化学链燃烧CO2捕集载氧体磨损
chemical looping combustionCO2 captureoxygen carrierattrition
《低碳化学与化工》 2024 (005)
50-61 / 12
国家自然科学基金(52176143).
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