低碳化学与化工2024，Vol.49Issue(5)：96-104,9.DOI:10.12434/j.issn.2097-2547.20230251
大电流密度下高性能析氢电催化剂研究进展
Research progress on high-performance hydrogen evolution reaction electrocatalysts under high current density
张奇 1郑东前 1刘馨璐 1杨勇 1梁欣 1董珊珊1
作者信息
- 1. 中国石化销售股份有限公司应用技术研究院,天津 300384
- 折叠
摘要
Abstract
H2 as a kind of clean energy is considered to be one of the most promising alternative energy sources to alleviate energy crisis and reduce environmental pollution.Using renewable energy to electrolyze water for H2 production is an important method for green hydrogen production.However,low current density and high energy consumption are the problems of industrial electrolysis of water for hydrogen production.Increasing the current density is the most direct way to increase the hydrogen production rate,but if the electrocatalyst is not optimized,increasing the current density will cause the increase of power consumption.Therefore,it is urgently needed to develop high-performance electrocatalysts for the hydrogen evolution reaction(hereinafter referred to as"HER")with low overpotential under high current density.Firstly,the mechanism of HER reaction in acidic and alkaline media was introduced,including Volmer-Heyrovsky and Volmer-Tafel,and the requirements of high performance electrocatalysts under high current density were put forward.Then,the research progress of precious metal and non-precious metal HER electrocatalysts in recent years from the aspects of single atom electrocatalysts,alloy electrocatalysts and heterostructure electrocatalysts were reviewed.Finally,the challenges and opportunities in the future for the development of HER electrocatalysts were discussed.关键词
电催化剂/析氢反应/大电流密度Key words
electrocatalyst/hydrogen evolution reaction/high current density分类
化学化工引用本文复制引用
张奇,郑东前,刘馨璐,杨勇,梁欣,董珊珊..大电流密度下高性能析氢电催化剂研究进展[J].低碳化学与化工,2024,49(5):96-104,9.
