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高分散水性碳纤维的制备

曹洪硕 周明正 敖静 乔伟静 陈玉姣 张水木 田艳红 张学军

中国造纸2024,Vol.43Issue(4):48-54,7.
中国造纸2024,Vol.43Issue(4):48-54,7.DOI:10.11980/j.issn.0254-508X.2024.04.005

高分散水性碳纤维的制备

Preparation of Highly Dispersed Aqueous Carbon Fibers

曹洪硕 1周明正 2敖静 2乔伟静 2陈玉姣 2张水木 2田艳红 1张学军1

作者信息

  • 1. 北京化工大学有机无机复合材料国家重点实验室,北京,100029
  • 2. 国家电投氢能科技发展有限公司,北京,100162
  • 折叠

摘要

Abstract

In this study,chitosan hydrochloride(CHI)and sodium dodecyl sulfate(SDS)were used to prepare modifier(CHI&SDS)that used to impregnate and modify the surface of BMH3 carbon fibers,in order to enhance the dispersing ability of the BMH3 carbon fibers in water.The effects of CHI/SDS mass ratio,mass concentration of CHI&SDS modifier,and fiber length on the dispersibility of modified BMH3 carbon fibers in water were systematically investigated,and the chemical structure and surface wettability of the modified BMH3 car-bon fibers were characterized and tested by X-ray photoelectron spectroscopy and dynamic contact angle test.The results showed that the dis-persion rate of modified BMH3 carbon fibers with fiber length of 5 mm in water could reach 96.2%,which was 87.5 percentage points high-er compared with that of unmodified BMH3 carbon fibers,after modified with a solution of CHI/SDS mass ratio=25∶1 at CHI&SDS modifier mass concentration of 0.15%.The number of oxygen-containing functional groups on the surface of the modified carbon fiber was significant-ly increased,and the water contact angle was significantly reduced,which was the reason for the improved dispersion of the carbon fiber and the basis for the successful preparation of highly dispersed aqueous carbon fiber.

关键词

BMH3碳纤维/碳纤维纸/表面改性/分散剂/分散性能

Key words

BMH3 carbon fiber/carbon fiber paper/surface modification/dispersant/dispersibility

分类

轻工纺织

引用本文复制引用

曹洪硕,周明正,敖静,乔伟静,陈玉姣,张水木,田艳红,张学军..高分散水性碳纤维的制备[J].中国造纸,2024,43(4):48-54,7.

基金项目

北京市科技计划(Z211100004521001). (Z211100004521001)

中国造纸

OA北大核心

0254-508X

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