聚合物人工固体电解质界面层的研究进展OA北大核心CSTPCD
Research progress of polymer artificial solid electrolyte interface layer
锂金属负极因具有极高的比容量(3 860 mAh/g)和低电化学电势(-3.04 V),成为可充电电池领域的研究热点.然而,锂金属的不稳定性会促使枝晶形成,在充放电过程中发生不可控的界面反应,导致生成的固体电解质界面(solid electrolyte interphase,SEI)层不稳定,进而影响电池循环寿命.通过锂金属负极表面引入聚合物人工SEI(ASEI),改善机械性能和电化学性能,从而制备长循环寿命和高能量密度的锂金属电池(LMBs).聚合物具有灵活度高及结构可设计等特点,是人工SEI的理想材料.概述了人工SEI的性质及作用,根据聚合物官能团类型和所起作用,系统总结了聚合物人工SEI的研究进展,并对未来的研究方向和发展前景作出展望.
Lithium metal anode has become a research hotspot in the field of rechargeable batteries due to its extremely high specific capacity(3 860 mAh/g)and low electrochemical potential(-3.04 V).However,the instability of lithium metal can promote the formation of dendrites,and the uncon-trolled interface reaction during charge and discharge can cause the generated solid electrolyte inter-phase(SEI)to be unstable,affecting the battery cycling life.By introducing artificial SEI(ASEI),the mechanical and electrochemical properties are improved.The goal is to prepare lithium metal batter-ies(LMBs)with long cycle life and high energy density.Polymers are highly flexible and capable of designing their structures to meet specific needs,making them ideal materials for artificial SEI.In this paper,the properties and functions of artificial SEI are summarized.According to the types and functions of different functional groups of polymers,the research progress of artificial SEI is summa-rized,and the future research direction and development prospect are prospected.
宋芊颖;胡桔溏;唐一帆;娜仁托雅;喻颖枝;旷桂超;陈立宝
中南大学粉末冶金国家重点实验室,湖南长沙 410083
动力与电气工程
人工固体电解质界面层聚合物锂金属电池
artificial solid electrolyte interface layerpolymerlithium metal battery
《电源技术》 2024 (005)
757-766 / 10
国家自然科学基金(U1904216);湖南省自然科学基金(2023JJ50012)
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