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钠离子电池过渡金属氧化物正极材料研究进展OA北大核心CSTPCD

Research progress on transition metal oxide cathode materials for so-dium ion batteries

中文摘要英文摘要

近年来,钠离子电池(SIBs)由于资源丰富、价格低廉等特点,逐渐成为储能领域的研究热点.然而,钠离子具有较大的离子半径和较慢的动力学速率,成为制约储钠材料发展的主要因素,而发展高性能的嵌钠正极材料是提高钠离子电池比能量和推进其应用的关键.围绕近几年氧化物类嵌钠正极材料体系方面的研究工作,综述了SIBs中过渡金属氧化物正极材料近十年的研究进展,并探讨过渡金属氧化物正极材料的结构和提高电化学性能的关系,分析了提高正极材料可逆容量、电压、结构稳定性的可能途径,为SIBs电极材料的发展提供参考.

In recent years,sodium ion battery(SIBS)has gradually become a research hotspot in the field of energy storage due to rich resources and low prices.However,sodium ions have a larger ion radius and slower kinetic rate,which have become the main factors restricting the development of so-dium storage materials.The development of high-performance sodium embedded cathode materials is the key to improving the specific energy of sodium ion batteries and promoting their applications.The research work on oxide based sodium embedded cathode material systems in recent years was focused on,the latest research progress of transition metal oxide based cathode materials in SIBs in the past decade was reviewed,and the relationship between improving the structure and electro-chemical performance of transition metal oxide based cathode materials was explored.Possible ways to improve the reversible capacity,voltage,and structural stability of cathode materials were ana-lyzed,and reference for the development of SIBs electrode materials was provided.

高士元;杜飞;张树祥;薛胜凡;张波;董捷;王金梅;蔡运功;韩婷婷;钱门祥

安徽理士电源技术有限公司,安徽淮北 235100

动力与电气工程

钠离子电池正极材料过渡金属氧化物材料

sodium ion batteriespositive electrode materialtransition metal oxide materials

《电源技术》 2024 (005)

792-805 / 14

10.3969/j.issn.1002-087X.2024.05.004

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