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不同比例CeO2包覆LNMO材料的电化学性能研究

董怡辰 王振波

电源技术2024,Vol.48Issue(5):843-849,7.
电源技术2024,Vol.48Issue(5):843-849,7.DOI:10.3969/j.issn.1002-087X.2024.05.010

不同比例CeO2包覆LNMO材料的电化学性能研究

Electrochemical properties of LNMO materials coated with different proportions of CeO2

董怡辰 1王振波2

作者信息

  • 1. 呼伦贝尔职业技术学院化学工程系,内蒙古呼伦贝尔 021000
  • 2. 哈尔滨工业大学化工与化学学院,黑龙江哈尔滨 150001
  • 折叠

摘要

Abstract

LiNi0.5Mn1.5O4(LNMO)cathode material was prepared by pH controlled co precipitation method,and SEM physical characterization showed that the material exhibited agglomerated spheri-cal particle morphology.Different proportions of CeO2 were used to coat and optimize the electro-chemical performance of LNMO cathode materials.The structure and morphology of CeO2-LNMO materials were characterized through physical tests.The electrochemical performance of CeO2-LNMO materials was analyzed through cycling,rate,voltammetry,and impedance tests.The CeO2-LNMO material with a CeO2 coating amount of 2%showed the best electrochemical performance.The first discharge specific capacities at high rate 5 C and 10 C were 108.8 and 97.6 mAh/g,and the capacity retention rate was 92.5%after 100 cycles at 1 C.CeO2 coating can enhance the conductivity of LNMO materials,improve the interfacial stability of materials,and optimize the electrochemical performance of LNMO cathode materials.

关键词

CeO2包覆/共沉淀法/LiNi0.5Mn1.5O4/电化学性能

Key words

CeO2 cladding/co-precipitation method/LiNi0.5Mn1.5O4/electrochemical properties

分类

信息技术与安全科学

引用本文复制引用

董怡辰,王振波..不同比例CeO2包覆LNMO材料的电化学性能研究[J].电源技术,2024,48(5):843-849,7.

基金项目

内蒙古自治区2023年度教育科学规划课题(NZJGH2023001) (NZJGH2023001)

电源技术

OA北大核心CSTPCD

1002-087X

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