化工学报2024，Vol.75Issue(4)：1105-1117,13.DOI:10.11949/0438-1157.20231407
镍催化可控/活性自由基聚合反应研究进展
Advances in nickel catalyzed controlled/living radical polymerization reactions
摘要
Abstract
Controlled/living radical polymerization reactions are developed to take the advantages of mild reaction conditions,well controlled reaction processes and accessible modification of polymer structures to build a variety of organic polymer materials with polar monomers as the starting materials in recent years,of which the fundamental mechanism is the reversible activation/deactivation between radical intermediates and transition-metal catalysts/chain transfer reagents.Because of the different oxidation states and the variable polymerization mechanisms,nickel catalysts have unique advantages in controlled/living radical polymerization.This article reviews the structure of catalysts,polymerization mechanisms and the structure of products of nickel catalyzed atom-transfer radical polymerization(ATRP)and organometallic mediated radical polymerization(OMRP).The future development direction and application prospects of controlled/living radical polymerization are prospected.关键词
镍/催化剂/自由基/聚合/可控/活性自由基聚合Key words
nickel/catalyst/radical/polymerization/controlled/living radical polymerization分类
化学化工引用本文复制引用
程骁恺,历伟,王靖岱,阳永荣..镍催化可控/活性自由基聚合反应研究进展[J].化工学报,2024,75(4):1105-1117,13.基金项目
国家自然科学基金青年科学基金项目(22301274) （22301274）
国家自然科学基金优秀青年科学基金项目(22222810) （22222810）
国家自然科学基金重点项目(22238007) （22238007）
