航空材料学报2024,Vol.44Issue(3):82-94,13.DOI:10.11868/j.issn.1005-5053.2023.000185
陶瓷基复合材料可磨耗环境障涂层制备及性能
Preparation and performance of abradable environmental barrier coating on ceramic matrix composites
摘要
Abstract
With the application of shrouds made of silicon carbide ceramic matrix composite(SiC-CMCs),the abradable coating technology suitable for SiC-CMCs is urgently needed.The four-layer structure of BSAS(Ba0.75Sr0.25Al2Si2O8)-polyester-based abradable environmental barrier coating(A/EBCs)was prepared by atmospheric plasma spraying.The influence of process parameters on the porosity and the structural evolution of the layer at 1300℃ were investigated.The phase structure,microstructure and coating composition were characterized by XRD,SEM,EDS and TEM respectively.The results show that the porosity of BSAS-polyester abradable top layer is 26.4%-36.8%.And the temperature-sensitive parameters of BSAS-polyester particles are primary gas(argon)flow,second gas(hydrogen)flow and spraying distance.In contrast,the speed-sensitive parameters are primary gas(argon)flow.The primary gas(argon)flow has the opposite effect on the particle temperature and velocity of the BSAS-polyester.The abradable surface layer is oxidized at 1300℃for 300 h and maintains monoclinic phase structure,stable stucture and composition,and locally precipitates spherical amorphous silicon oxide particles.Furthermore,the coating abradability was evaluated by high-temperature and high-speed scraping test.Nano-scale Ni-based superalloy particles adhesion on the surface of the coating are found,and the blade incursion depth ratio(IDR)is 20%,which meets the requirements of the abradable sealing coating.关键词
可磨耗环境障涂层/等离子喷涂/碳化硅陶瓷基复合材料/BSAS/高温性能Key words
abradable environmental barrier coating(A/EBCs)/plasma spraying/silicon carbide ceramic matrix composites(SiC-CMCs)/BSAS/high temperature performance分类
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袁世峰,郭婧,郭孟秋,赵春玲,崔永静,焦健..陶瓷基复合材料可磨耗环境障涂层制备及性能[J].航空材料学报,2024,44(3):82-94,13.基金项目
航空发动机及燃气轮机基础科学中心项目(P2022-B-Ⅳ-003-001) (P2022-B-Ⅳ-003-001)