常州大学学报(自然科学版)2024,Vol.36Issue(3):10-17,8.DOI:10.3969/j.issn.2095-0411.2024.03.002
合成温度对Cs3Cu2Cl5荧光性能及稳定性的影响
Effect of synthesis temperature on the photoluminescence and stability of Cs3Cu2Cl5
摘要
Abstract
Green fluorescent lead-free copper based perovskite Cs3Cu2Cl5 particles were synthesized by hot injection method.The photoluminescence quantum yield(Φ),lifespan and enviromental stability of Cs3Cu2Cl5 was studied under different synthesis conditions by characterizing its structure,morphol-ogy,and fluorescence performance.The result showed that the Cs3Cu2Cl5 perovskite particles synthe-sized under the reaction temperature of 150 ℃ had the highest photoluminescence quantum yield,and reached the highest value about 43.5%in the fourth week,with the fluorescence lifetime about 95 μs.After being stored in air for one month,the original crystal structure and good fluorescence properties were still maintained,demonstrating good stability.关键词
无铅钙钛矿/铜基钙钛矿/Cs3Cu2Cl5/荧光性能/稳定性Key words
lead-free perovskite/copper-based perovskite/Cs3Cu2Cl5/fluorescence properties/stability分类
航空航天引用本文复制引用
孙天龙,胡超,孙一新,张嵘,盛扬..合成温度对Cs3Cu2Cl5荧光性能及稳定性的影响[J].常州大学学报(自然科学版),2024,36(3):10-17,8.基金项目
中国博士科学基金资助项目(2019M651677). (2019M651677)