棉纺织技术2024，Vol.52Issue(6)：41-48,8.
铅铆钉钙钛矿原位生长及荧光纤维湿法纺丝研究
Study on perovskite lead rivet in-situ growth and fluorescent fiber wet spinning
摘要
Abstract
In order to improve the stability of lead halide perovskite,inhibit lead ion release and reduce the potential biological toxicity threat,lead rivet growth perovskite method was put forward.The lead ion capture process was introduced at the initial stage of crystal growth to solve the problem of lead ion leakage and further improve its stability through the atomic layer deposition strategy,so that it could be safely suitable for the fluorescent wet spinning process.The results showed that the perovskite nanoparticles with the lead rivet strategy could greatly reduce the lead ion emission even under complete dissociation conditions.The fluorescent quantum yield was reached 56.68%,and the lead ion mass concentration of prepared fluorescent fiber for 5 days continuous soaking was only 1.58 μg/L,which could reaching the standard for drinking water.It is considered that the scheme could solve the instability problem of lead halogen perovskite in water,and wet spinning method could be used to prepare perovskite fluorescent fibers with excellent fluorescence stability,chemical stability and biological safety performance.Its breaking elongation was reached 364.72%.It has excellent fiber toughness and weaving performance.关键词
钙钛矿/铅铆钉/原子层沉积/荧光纤维/湿法纺丝Key words
perovskite/lead rivet/atomic layer deposition/flurescent fiber/wet spinning分类
轻工业引用本文复制引用
王涵龙,朱士凤,高飞红,曲丽君,游超瑜..铅铆钉钙钛矿原位生长及荧光纤维湿法纺丝研究[J].棉纺织技术,2024,52(6):41-48,8.基金项目
国家自然科学基金面上项目(21972117) （21972117）
山东省自然科学基金(ZR2021QE201,ZR2023ME157) （ZR2021QE201,ZR2023ME157）
青岛博士后创新项目(QDBSH20220202210) （QDBSH20220202210）
青岛大学生物纤维和生态纺织品国家重点实验室研究基金(ZKT45) （ZKT45）
