无机材料学报2024，Vol.39Issue(5)：457-466,10.DOI:10.15541/jim20230448
大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展
Progress on Large-area Organic-inorganic Hybrid Perovskite Films and Its Photovoltaic Application
摘要
Abstract
Recently,organic-inorganic hybrid perovskite solar cells have demonstrated a broad commercial prospect due to their high photoelectric conversion efficiency(PCE)and low fabricating costs.During the past decades,the highest reported PCE of small-area(＜1 cm2)perovskite solar cells(PSCs)rose to 26.10％,and those of large-area(1-10 cm2),mini-module level(10-800 cm2)and module level(＞800 cm2)PSCs increased to 24.35％,22.40％and 18.60％,respectively.The performance of PSCs decreases dramatically with the area increasing due to limitation of the deposition method and the poor quality of large-area perovskite films.Spin-coating method is not suitable for actual industrial production,while the scalable deposition methods including blade-coating and slot-die coating still face the difficulty of precisely controlling nucleation and crystallization of the perovskite films with large area.This review summarized preparation methods of large-area perovskite films,and discussed the film-forming mechanism and strategies for high-quality perovskite films.Finally,relevant outlooks on technologies and applications for large-area PSCs with high performances and stabilities were analyzed.This review is expected to provide insights on the research of large-area PSCs with high performance.关键词
钙钛矿薄膜/钙钛矿太阳能电池/大面积/成膜控制/综述Key words
perovskite film/perovskite solar cell/large area/film-forming control/review分类
化学化工引用本文复制引用
张慧,许志鹏,朱从潭,郭学益,杨英..大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展[J].无机材料学报,2024,39(5):457-466,10.基金项目
国家重点研发计划(2023YFC3906103) （2023YFC3906103）
湖南省自然科学基金面上项目(2022JJ30757) （2022JJ30757）
清远市创新创业科研团队项目(2018001)National Key R&D Program of China(2023YFC3906103) （2018001）
Hunan Provincial Natural Science Foundation(2022JJ30757) （2022JJ30757）
Qingyuan Innovation and Entrepreneurship Research Team Program(2018001) （2018001）
