云南化工2024，Vol.51Issue(5)：7-10,4.DOI:10.3969/j.issn.1004-275X.2024.05.02
光/电催化3-氮杂-1,5-二烯合成4-吡咯啉-2-酮的研究进展
Advances in 4-Pyrrolin-2-one Synthesis from 3-Aza-1,5-dienes Enabled by Photocatalysis/Electrochemistry
摘要
Abstract
4-Pyrrolin-2-ones,which usually exhibit significantbiological activities,are core structural elements in natural alkaloids and syn-theticpharmaceuticals.Traditionally,4-pyrrolin-2-ones were prepared under harsh conditions including an elevated temperature,and a noble metal catalyst was required.Recently,it has been found that functionalized 4-pyrrolin-2-ones can be synthesized in one step from readily a-vailable 3-aza-1,5-dienes,and that photocatalytic and electrocatalytic methods are particularly green,mild and in line with the concept of green chemistry and with the"two-carbon"goal.This review provides an overview of the advancements in 4-pyrrolin-2-one synthesis from 3-aza-1,5-dienes enabled by photocatalysis or electrochemistry while categorizing the reactions based on reaction types.关键词
4-吡咯啉-2-酮/光催化/合成电化学/烯烃Key words
4-Pyrrolidine-2-ones/Photocatalysis/Synthetic electrochemistry/Alkenes分类
化学引用本文复制引用
龚开兴,马迎春,余平,梁德强..光/电催化3-氮杂-1,5-二烯合成4-吡咯啉-2-酮的研究进展[J].云南化工,2024,51(5):7-10,4.基金项目
国家自然科学基金项目(22061024),云南省兴滇英才青年人才专项(YNWR-QNBJ-2018-133),云南贵金属实验室基础研究项目(YPML-2023050262),昆明学院科学研究项目(XPZJ2204). （22061024）
