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污染土壤稳定化处理后铬返溶影响因子的研究OA

Study on the Driving Factors of Cr Re-dissolution after Stabilizing Contaminated Soil

中文摘要英文摘要

探究了稳定化处理后污染土壤中Cr的返溶影响因子.结果表明,对返溶释放促进作用最大的条件为:水淹、水溶液pH为 1、40℃、一周鼓3d氧气,这时土壤中Cr(VI)由 10.00 mg/kg增至31.47 mg/kg,浸出液中总铬由0.15 mg/L增至0.36 mg/L.40℃、水淹、水溶液pH=1、水溶液pH=12、一周鼓3 天氧气处理后Cr的有效态质量分数分别增加0.02%、1.46%、2.12%、0.03%、0.85%.含水率是影响污染土壤稳定化处理后Cr返溶的主要因素,pH为次要因素.在不同pH条件下,稳定化处理后的土壤中Cr的释放量皆与二级动力学方程拟合度最高.

The main research focuses on the driving factors of Cr re-dissolution after stabilization treatment.The results showed that the condi-tions with the greatest promoting effect of re-dissolution were water flooding,pH of acid rain at 1,temperature of 40℃,oxygen bubbling for 3 days perweek,Cr(VI)in the soil increasing from10.00 mg/kg to31.47 mg/kg,and total Crin the leaching solution increasing from0.15 mg/L to 0.36 mg/L.The effective content of Cr increased by 0.02%,1.46%,2.12%,0.03%and 0.85%after treatment under conditions of 40℃,water flooding,pH of acid rain at 1,pH of acid rain at 12,and 3 days of oxygen blowing per week.The moisture content is the main factor affecting the Cr re-dissolution after stabilization treatment of contaminated soil,while the pH of acid rain is the secondary factor.The release of Cr in the stabilized soil showed the highest degree of fit with the second-order kinetic equation under different acid rain pH conditions.

李义伟;曾娟;李立;魏来;钱子妍

长沙矿冶研究院有限责任公司,湖南 长沙 410012

环境科学

土壤稳定化铬污染重金属返溶

SoilStabilizationChromium PollutionHeavy MetalsRe-dissolution

《云南化工》 2024 (005)

39-45 / 7

10.3969/j.issn.1004-275X.2024.05.10

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