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偏高岭土改性轻烧氧化镁基磷酸镁水泥的3D打印性能

李楠 钟建军 邓永杰 梁云 万德田 李维红 李栋伟

硅酸盐通报2024,Vol.43Issue(5):1663-1672,10.
硅酸盐通报2024,Vol.43Issue(5):1663-1672,10.

偏高岭土改性轻烧氧化镁基磷酸镁水泥的3D打印性能

3D Printing Performance of Metakaolin Modified Light Burnt Magnesia-Based Magnesium Phosphate Cement

李楠 1钟建军 1邓永杰 1梁云 1万德田 2李维红 3李栋伟1

作者信息

  • 1. 大连大学复杂结构系统灾害预测与防治辽宁省重点实验室,大连 116622||大连大学建筑工程学院,大连 116622
  • 2. 中国建筑材料科学研究总院有限公司,北京 100024
  • 3. 大连大学复杂结构系统灾害预测与防治辽宁省重点实验室,大连 116622||大连大学建筑工程学院,大连 116622||大连学庆铭锋数控技术有限公司,大连 116622
  • 折叠

摘要

Abstract

In this paper,the 3D printing light burned magnesia-based magnesium phosphate cement material was realized by using the self-developed integrated building 3D printing equipment with mixed stirring and extrusion function.The effect of different metakaolin(MK)content on the properties of 3D printing light burned magnesia-based magnesium phosphate cement was investigated,and combined with XRD and SEM test to further analyze the influence of MK content on the hydration products and crystal appearance of light burnt magnesia-based magnesium phosphate cement.The results show that the setting time and mechanical properties of 3D printing light burnt magnesia-based magnesium phosphate cement increase first and then decrease with the increase of MK content.When MK replaces 4%to 6%of the total mass of magnesia and potassium dihydrogen phosphate,the addition of MK effectively improves the printing performance of light burnt magnesia-based magnesium phosphate cement paste.At this time,the light burned magnesia-based magnesium phosphate cement has good extrusion performance,construction performance and mechanical properties,which can meet the application requirements of 3D printing.The addition of MK does not change the crystal composition of the hydration products of light burnt magnesia-based magnesium phosphate cement,but produces a large number of amorphous amorphous hydration products,which can further fill the gap between hydration products and particles and improve the compactness of structure.

关键词

轻烧氧化镁/偏高岭土/磷酸镁水泥/3D打印/打印性能/力学性能

Key words

light burned magnesia/metakaolin/magnesium phosphate cement/3D printing/printing performance/mechanical property

分类

建筑与水利

引用本文复制引用

李楠,钟建军,邓永杰,梁云,万德田,李维红,李栋伟..偏高岭土改性轻烧氧化镁基磷酸镁水泥的3D打印性能[J].硅酸盐通报,2024,43(5):1663-1672,10.

基金项目

大连市重点科技研发项目(2023YF23WZ045) (2023YF23WZ045)

辽宁省教育厅科学研究经费项目(LJKZ1177) (LJKZ1177)

国家自然科学基金重点项目(52032011) (52032011)

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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