环境工程学报2024，Vol.18Issue(4)：1096-1103,8.DOI:10.12030/j.cjee.202407033
炼油污水处理厂二沉出水中溶解性有机物组分分析
Characterization of four fractions of dissolved organic matters in secondary effluent of refinery wastewater treatment plant
摘要
Abstract
The dissolved organic matter(DOM)in the effluent from the secondary effluent of a refinery wastewater treatment plant was separated by MCX/MAX extraction column,and four sub-components including hydrophobic acidic component(HOA),hydrophobic alkaline component(HOB),hydrophobic neutral component(HON)and hydrophilic substance(HIS)were obtained.3D-EEM and ESI FT-ICR MS were used to analyze each component.The results showed that specific fluorescence peaks of phenolic substances and petroleum substances existed in the refined wastewater,there were more compounds in HOA component,which mainly was CHOS substances;less substances were detected in HOB component,which mainly was O3S1 substances,and more CHOS,CHON and CHO substances were observed in HON component.This study makes an in-depth analysis of DOM in the effluent of refined wastewater,providing a reference for treatment process optimization and environmental impact assessment of external drainage of refinery wastewater.关键词
炼油污水/二沉出水/三维荧光/分子组成Key words
refinery wastewater/secondary effluent/3D-EEM/molecular composition分类
资源环境引用本文复制引用
王鑫,肖向群,吴倩,姜峻韬,宁潇宇,王庆宏,陈春茂..炼油污水处理厂二沉出水中溶解性有机物组分分析[J].环境工程学报,2024,18(4):1096-1103,8.基金项目
中国石油科技创新基金(2020D-5007-0505) （2020D-5007-0505）
中国石油大学(北京)科研启动基金(2462021YJRC016) （北京）
国家自然科学基金面上项目(22176220) （22176220）
