石油化工高等学校学报2024,Vol.37Issue(3):17-24,8.DOI:10.12422/j.issn.1006-396X.2024.03.003
基于不同路线合成环己基苯的催化剂研究进展
Research Progress of Catalysts for Cyclohexylbenzene Synthesis Based on Different Routes
摘要
Abstract
Cyclohexylbenzene(CHB)is an important chemical intermediate with special physicochemical properties.It can be used as electrolyte additive for lithium ion battery.A small amount can prevent overcharging and ensure battery cycle performance and life.CHB can generate another important organic chemical product,cyclohexanone,when used in the synthesis of phenol through peroxidation reaction.Introduced the catalysts used in three methods for synthesizing CHB.These three methods include Fouke alkylation of benzene with alkylation reagent,selective hydrogenation of biphenyl,and alkylation of benzene with hydrogen.It is pointed out that the development of zeolite molecular sieve catalysts with high acid content and high mesoporous volume is the key to the preparation of CHB by benzene hydroalkylation.关键词
环己基苯/加氢烷基化/催化剂/离子液体/傅克烷基化Key words
Cyclohexylbenzene/Hydroalkylation/Zeolites/Ionic liquid/Friedel-Crafts alkylation分类
化学化工引用本文复制引用
唐伟建,王钰佳,孙娜,王海彦..基于不同路线合成环己基苯的催化剂研究进展[J].石油化工高等学校学报,2024,37(3):17-24,8.基金项目
辽宁省教育厅科研项目(L2019014). (L2019014)