大学化学2024,Vol.39Issue(5):20-26,7.DOI:10.3866/PKU.DXHX202309055
Dess-Martin试剂的制备及在氧化环己醇中的应用
Preparation of Dess-Martin Reagent and Its Application in Oxidizing Cyclohexanol
摘要
Abstract
Preparation of cyclohexanone is a classic"hands-on"organic chemistry experiment widely used in undergraduate teaching.However,conventional experiments often involve the use of non-environmentally friendly high-cost heavy metal oxidants,limiting the teaching process to the development of students'experimental skills.In response to this,we have transformed the experiment into a design-oriented approach.Students are tasked with consulting literature,researching,and exploring greener and more environmentally friendly oxidation systems.By evaluating the merits of various oxidation systems,determining the types of oxidants,and designing experimental procedures,students complete the experiment.This innovative approach enhances the experiment's complexity,promotes innovation,and introduces challenges.It not only solidifies students'practical laboratory skills but also cultivates their ability to discover,analyze,and solve problems,fostering innovative thinking and awareness of green chemistry.关键词
设计型实验/绿色氧化/Dess-Martin试剂/环己酮的制备Key words
Design experiment/Green oxidation/Dess-Martin reagent/Preparation of cyclohexanone分类
社会科学引用本文复制引用
温桃,张涛,孙昌果,刘金宇..Dess-Martin试剂的制备及在氧化环己醇中的应用[J].大学化学,2024,39(5):20-26,7.基金项目
成都理工大学教改项目(2022YJG020) (2022YJG020)