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Dess-Martin试剂的制备及在氧化环己醇中的应用

温桃 张涛 孙昌果 刘金宇

大学化学2024,Vol.39Issue(5):20-26,7.
大学化学2024,Vol.39Issue(5):20-26,7.DOI:10.3866/PKU.DXHX202309055

Dess-Martin试剂的制备及在氧化环己醇中的应用

Preparation of Dess-Martin Reagent and Its Application in Oxidizing Cyclohexanol

温桃 1张涛 1孙昌果 1刘金宇1

作者信息

  • 1. 成都理工大学材料与化学化工学院,成都 610059
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摘要

Abstract

Preparation of cyclohexanone is a classic"hands-on"organic chemistry experiment widely used in undergraduate teaching.However,conventional experiments often involve the use of non-environmentally friendly high-cost heavy metal oxidants,limiting the teaching process to the development of students'experimental skills.In response to this,we have transformed the experiment into a design-oriented approach.Students are tasked with consulting literature,researching,and exploring greener and more environmentally friendly oxidation systems.By evaluating the merits of various oxidation systems,determining the types of oxidants,and designing experimental procedures,students complete the experiment.This innovative approach enhances the experiment's complexity,promotes innovation,and introduces challenges.It not only solidifies students'practical laboratory skills but also cultivates their ability to discover,analyze,and solve problems,fostering innovative thinking and awareness of green chemistry.

关键词

设计型实验/绿色氧化/Dess-Martin试剂/环己酮的制备

Key words

Design experiment/Green oxidation/Dess-Martin reagent/Preparation of cyclohexanone

分类

社会科学

引用本文复制引用

温桃,张涛,孙昌果,刘金宇..Dess-Martin试剂的制备及在氧化环己醇中的应用[J].大学化学,2024,39(5):20-26,7.

基金项目

成都理工大学教改项目(2022YJG020) (2022YJG020)

大学化学

1000-8438

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