硅酸盐学报2024，Vol.52Issue(6)：2162-2174,13.DOI:10.14062/j.issn.0454-5648.20230722
水滑石超级电容器电极材料层间距调控研究进展
Research Progress on Layered Double Hydroxide Electrode Materials for Supercapacitors
摘要
Abstract
Supercapacitors have attracted recent attention because of their high power density,fast charging and discharging capability,long cycle life,and good stability.However,the generally low energy density of supercapacitors restricts their applications.The electrode material is the most critical part in the supercapacitor and significantly affects the performance.In recent years,a rational design of electrode materials is proved to be an effective way to improve the capacitance performance of supercapacitors.Among many electrode materials,layered double hydroxide(i.e.,hydrotalcite and hydrotalcite-like)has the advantages of adjustable morphology and composition,high theoretical specific capacitance,low cost,easy synthesis and considerable energy density and power density,etc.,and emerges in the field of supercapacitor electrode materials.The unique two-dimensional structure of the layered double hydroxide(LDH)and its energy storage mode through electrolyte ions embedded and dislodged in the interlayer dictate that an interlayer spacing modulation is an effective method to improve its capacitance performance.Enhancing the utilization of electrochemically active sites between LDH layers and reducing the ion transport velocity resistance via regulating the layer spacing become a commonly used and effective structural modulation method for two-dimensional electrode materials such as LDH. This review summarized the research progress on the application of LDH interlayer spacing regulation in the field of supercapacitors,introduced the structure of LDH,the energy storage mechanism,and the advantages of LDH as an electrode material,and described the influencing factors and the advantages and disadvantages about the interlayer spacing regulation from the two different perspectives of the ion-exchange method and the one-step synthesis method,respectively.The target anion intercalation in the two methods concerns the anion charge density and anion concentration in the reaction system.The interlayer spacing values of different guest intercalated LDH,such as inorganic anions,organic anions,and molecules,were discussed.The factors affecting interlayer spacing and capacitance performance were summarized.A small interlayer spacing significantly inhibits ion diffusion and charge transport,which is not conducive to achieving a high capacitance performance.Organic anion intercalation is more likely to achieve a larger interlayer spacing and a higher capacitance performance.Appropriate interlayer objects and interlayer spacing are crucial for achieving a high capacitance performance.The influence of metal cations ratio on the interlayer spacing and capacitance performance was evaluated,and three methods for regulating metal cations were summarized.The ratio of divalent and trivalent cations in the synthesis process can be adjusted to achieve the control of positive charge concentration in the basal layer and the control of interlayer force,thus controlling the interlayer spacing.The oxidation of divalent cations during or after synthesis is controlled to achieve a positive charge density.Selecting cations of different radii to synthesize LDH affects the distribution of basal layer charges,thereby affecting the interlayer spacing.This review elaborated on the method of adding intercalation agents during the process of regulating interlayer spacing,which can simultaneously increase the interlayer spacing and load mass,and is of great significance for obtaining high load and high capacitance electrodes.This review outlined common methods for improving capacitance performance by regulating interlayer spacing and the underlying mechanisms for improving the capacitance performance,playing an important role in promoting the in-depth research and application of LDH electrode materials. Summary and prospects Some prospects for future development were provided.In the future,with the continuous development of precise temperature control,uniform,and rapid heating synthesis technologies such as microwave synthesis,the combination of artificial intelligence control technology and synthesis equipment,the advancement of multi index observation in-situ experimental technology,and the precise observation and control of synthesis heating rate,temperature field,and concentration field are effective ways to achieve precise synthesis of hydrotalcite and precise control of interlayer spacing.And it is expected to achieve precise control of the types,quantities,and layout of interlayer objects according to demand.The influences of interlayer object types,quantities,arrangement attitudes,and pores on the electrolyte ion transport,and the related mechanism on the interlayer active site electrochemical reactions,and the related mechanism on the interlayer spacing and layer structure evolution can be investigated more accurately.The combination of multi-index observation in-situ synthesis experimental technology with the first-principles,molecular dynamics,and machine learning simulation methods can be ultilized to analyze the microstructure,electrochemical reactions,and other processes.关键词
水滑石/超级电容器电极材料/层间距调控/电容性能Key words
layered double hydroxide/supercapacitor/interlayer spacing regulation/capacitor performance分类
信息技术与安全科学引用本文复制引用
王晓亮,黄传辉,杨绍斌,高靖淞,宋晓琦,张一波,潘奎,王宏伟,郭力歌,李盼盼,刘忆..水滑石超级电容器电极材料层间距调控研究进展[J].硅酸盐学报,2024,52(6):2162-2174,13.基金项目
国家自然科学基金(51974152). （51974152）
