净水技术2024，Vol.43Issue(z1)：366-372,7.DOI:10.15890/j.cnki.jsjs.2024.s1.053
液相色谱串联质谱法快速测定水中敌百虫等6种农药
Fast Determination of 6 Pesticides(Such as Trichlorfon)in Water by LC-MS/MS
摘要
Abstract
With the implementation of the Standards of Drinking Water Quality(GB 5749-2022),more and more pesticides have been included in drinking water quality monitoring which haven't efficient detection methods.Thus,a fast detection method including 6 pesticides(trichlorfon,thiophanate-methyl,simetryne,metalaxyl,isoprothiolane and trifluralin)was established.Samples were detected bydirect injection-high performance liquid chromatography-tandem mass spectrometryafter being filtered by PTFE membrane.Detection limits of this method were ranged from 0.02 μg/L to 3.1 μg/L.The method recoveries were 60.5％～120.3％in pure water,69.3％～129.8％in drinking water and 75.1％～127.2％in surface water.Relative standard deviation were 0.5％～6.2％in pure water,0.4％～7.5％in drinking water and 0.5％～5.1％in surface water.Four differentfilter membranes were tested on the effect of method recoveriesand the PTFE membrane was selected.The method can well applied in routine and emergency detectionof drinking water and surface water with high efficiency and reliability.关键词
直接进样/敌百虫/甲基硫菌灵/西草净/甲霜灵/稻瘟灵/氟乐灵/饮用水/地表水Key words
direct injection/trichlorfon/thiophanate-methyl/simetryne/metalaxyl/isoprothiolane/trifluralin/drinking water/surface water分类
建筑与水利引用本文复制引用
蔡海芸..液相色谱串联质谱法快速测定水中敌百虫等6种农药[J].净水技术,2024,43(z1):366-372,7.基金项目
国家重点研发计划:长江、黄河流域饮用水源高风险污染物工艺可处理性研究任务(2021YFC3200805-3) （2021YFC3200805-3）
上海市科委:超大城市饮用水韧性及品质提升关键技术研究及示范(23DZ1203001) （23DZ1203001）
