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导热吸波双功能粉体改性设计研究OA北大核心CSTPCD

Study on modification and design of thermal conductive and microwave absorbing dual-functional powders

中文摘要英文摘要

以氧化铝(Al2O3)为导热粉体,铁硅铝(FeSiAl)为吸波粉体,采用十二烷基三乙氧基硅氧烷(C12)为粉体表面改性剂,设计不同配比及粒径的导热吸波双功能粉体,填充于硅油体系制备导热吸波垫片,开发出导热吸波双功能一体化材料.结果表明,C12对Al2O3、FeSiAl均具有良好的亲油改性效果;当Al2O3∶FeSiAl质量比为20∶80时,导热吸波垫片的导热系数最高可达到5.92 W/m·K,并在4.8~6.5 GHz区间拥有良好的吸波能力,在保证高导热的前提下,赋予复合材料优异吸波能力;此外,所制试样易于压缩,在50 psi压缩应力条件下即可达到50%压缩形变,便于实际装配应用.

A type of thermal conductive and microwave absorbing dual-functional powders were designed with different ra-tios and particle sizes using aluminum oxide(Al2O3)as thermal conductivity powders,sendust(FeSiAl)as microwave absorbing powders,and dodecyltriethoxysilane(C12)as a modifier.The resultant dual-functional powders were filled in a silicone oil to prepare a thermal conductive and microwave absorbing pad,thus developing a series of thermal conductiv-ity absorbing dual-function integrated materials.The results indicated that C12 generated a good lipophilic modification effect on Al2O3 and FeSiAl.The thermal conductive and microwave absorbing pad showed a thermal conductivity of 5.92 W/(m·K)at a Al2O3/FeSiAl mass ratio of 20∶80,exhibiting a good absorbing capability in the frequency range of 4.8~6.5 GHz.Ensuring a high thermal conductivity,the as-prepared powders were endowed with a wave-absorbing ca-pability.Meanwhile,it is easy for the powders to be compressed and convenient for practical assembly applications,and their 50-psi compression stress reached a compression strain of 50% .

高玮;熊昌义;韩飞;孔泥早;颜渊巍

株洲时代新材料科技股份有限公司,湖南 株洲 412007湖南大学先进炭材料及应用技术湖南省重点实验室,长沙 410082

化学工程

导热吸波改性压缩

thermal conductivitymicrowave absorbingmodificationcompression

《中国塑料》 2024 (006)

19-24 / 6

湖南创新型省份建设专项项目(2022GK2034)

10.19491/j.issn.1001-9278.2024.06.003

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