电化学（中英文）2024，Vol.30Issue(5)：174-182,9.DOI:10.61558/2993-074X.3438
钯催化电化学烯丙位4-吡啶化反应中的配体作用研究
Comparison of Ligands in Palladium-catalyzed Electrochemical Allyl 4-Pyridinylation
摘要
Abstract
4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations.Conventionally,the reac-tion proceeds via an open-shell radical cross-coupling pathway.Following our previous study,in this work,we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions.The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investi-gated.关键词
电化学/钯催化/膦配体/吡啶化/烯丙基Key words
Electrochemistry/Palladium/Phosphine/Pyridinylation/Allyl引用本文复制引用
丁伟杰,杨春晖,冯钟涛,陆仕荣,程旭..钯催化电化学烯丙位4-吡啶化反应中的配体作用研究[J].电化学（中英文）,2024,30(5):174-182,9.基金项目
This work was supported by the National Natu-ral Scieence Foundation of China(Nos.22031008 and 22071105). （Nos.22031008 and 22071105）
