环境空气中铵盐与PM2.5浓度爆发性增长特征研究OACSTPCD
Research on Characteristics of Explosive Growth of Ammonium Salt and PM2 5 Concentration in Ambient Air
基于大气污染防治的严峻性,特别是细颗粒物污染仍是关注的重点,选取四川省乐山市作为研究对象,对2021年频繁出现的PM2.5浓度爆发性增长进行研究.结合主要气态污染物和铵根离子、硫酸根离子、硝酸根离子浓度变化特征分析得出:乐山市的PM2.5浓度爆发性增长与二次无机阳离子(NH4+)、阴离子(SO42-、NO3-)有很好的关联性,Pearson相关系数最大达到0.939、0.954和0.832;同时PM2.5还与SO2、CO等一次污染物呈显著正相关,Pearson相关系数最大达到0.940和0.952,燃煤源影响达到案例统计数量的90%.经地面风向数据与铵根离子浓度辐合进一步推断出污染来源与城市南面的大型燃煤、涉氨类企业排放相关,为进一步的污染防控和精准治理提供指引.
Because of the severity of air pollution control,fine particulate pollution is especially the focus of attention.Leshan,Sichuan was selected as the research object in this paper to study the explosive growth of PM2 5 concentration that occurred frequently in 2021.According to the analysis on characteristics of major gaseous pollutants and concentration changes of ammonium ions,sulfate ions and nitrate ions,it was concluded that:the explosive growth of PM2.5 concentration in Leshan was significantly correlated with the secondary inorganic cation(NH4+)and anion(SO42-and NO3-),and the maximum Pearson correlation coefficients were 0.939,0.954,and 0.832;PM2 5 was also significantly positively correlated with primary pollutants,such as SO2 and CO;and the maximum Pearson correlation coefficients were 0.940 and 0.952;and the impact of coal sources reached 90%of the case statistics.Based on the convergence of surface wind direction data and ammonium ion concentration,it is further inferred that the pollution source is related to the emission of large coal-burning and ammonia-related enterprises in the south of Leshan,providing guidance for further pollution prevention and control and precise control.
龚韬;张勇;陈贝;齐国伟;李嘉琪;江南
四川省乐山生态环境监测中心站,四川乐山 614000乐山市气象局气象台,四川乐山 614000
环境科学
PM2.5铵盐污染防控
PM2.5ammonium saltpollution prevention and control
《四川环境》 2024 (003)
12-18 / 7
乐山市重点科技计划项目(22SZD009、23GZD007).
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