人工晶体学报2024，Vol.53Issue(6)：959-966,8.
Ib型金刚石单晶生长及合成腔体温度场分布研究
Study on the Growth of Type-Ib Diamond Single Crystal and the Temperature Field Distribution in the Synthesis Cavities
摘要
Abstract
In this paper,type-Ib diamond single crystals,using two different sizes of synthesis cavities of φ15 mm andφ30 mm,were synthesized under 5.7 GPa,1 560～1 600 K,and the temperature field distributions of the two sizes of synthesis cavities were studied using finite element method(FEM).Firstly,the temperature field distributions of two different sizes of synthesis cavities were simulated using finite element method.The average radial temperature gradient and average axial temperature gradient of the φ15 mm synthesis cavity are 0.573 and 5.700 K/mm,respectively.The average radial temperature gradient and average axial temperature gradient of the φ30 mm cavity are 0.093 and 2.280 K/mm,respectively.The simulation results reveal that the uniformity of the temperature field in the φ30 mm synthesis cavity is significantly better than that in the φ15 mm synthesis cavity.Secondly,the reproducible growth of high-quality type-Ib diamond large single crystals was achieved using both synthesis cavities mentioned above.The φ15 mm synthetic cavity is difficult to achieve the growth of high-quality type-Ib diamond single crystals weighing more than 1.2 ct(1 ct=0.2 g),while the φ30 mm synthetic cavity is more suitable for the growth of large-size high-quality type-Ib diamond single crystals.Furthermore,the scanning electron microscopy(SEM)test results show that the surface flatness of high-quality type-Ib diamond single crystals grown using two different sizes of synthesis cavities in this study is good,and the expansion of the synthesis cavity has no significant effect on the crystal quality of Ib diamond single crystal surface.Finally,Raman spectrum test results show that the crystal quality of polycrystalline diamond deteriorates,and other diamond single crystal samples synthesized by two kinds of synthesis cavity in this study have better crystal quality.This research has certain academic reference value for the design of large size synthesis cavity of gem grade diamond single crystal,the growth of large size diamond single crystal,and the perfection of polycrystalline diamond single crystal synthesis technology.关键词
Ib型金刚石/高温高压/温度梯度法/触媒/温度场/多晶Key words
type-Ib diamond/high pressure and high temperature/temperature gradient method/catalyst/temperature field/polycrystal分类
化学化工引用本文复制引用
肖宏宇,周振翔,李勇,田昌海,张蔚曦,王强,肖政国,王应,金慧,鲍志刚..Ib型金刚石单晶生长及合成腔体温度场分布研究[J].人工晶体学报,2024,53(6):959-966,8.基金项目
国家自然科学基金(12064038) （12064038）
贵州省科技厅项目(黔科合基础-ZK[2023]一般467,ZK[2021]重点019,ZK[2021]一般021,ZK[2021]一般034,ZK[2021]一般031,ZK[2023]重点049) （黔科合基础-ZK[2023]一般467,ZK[2021]重点019,ZK[2021]一般021,ZK[2021]一般034,ZK[2021]一般031,ZK[2023]重点049）
铜仁学院科研启动基金(trxyDH2221) （trxyDH2221）
