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基于CDs@SiNWs的光电化学免疫传感器构建及性能研究

黄粤夷 直士博 李慧珺

有色金属材料与工程2024,Vol.45Issue(3):32-37,6.
有色金属材料与工程2024,Vol.45Issue(3):32-37,6.DOI:10.13258/j.cnki.nmme.20230221001

基于CDs@SiNWs的光电化学免疫传感器构建及性能研究

Construction and performance of photoelectrochemical immunosensor based on CDs@SiNWs

黄粤夷 1直士博 1李慧珺1

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093
  • 折叠

摘要

Abstract

A novel label-free photoimmunosensor was prepared by metal-assisted chemical etching of highly oriented silicon nanowire arrays(SiNWs)combined with carbon dots(CDs)modification for the detection of cardiac troponin I(cTnI).N-type SiNWs were used as photoanodes to obtain a strong photoelectric signal response.CDs are loaded on the surface of SiNWs by the spin-coating method.CDs can improve the photoelectric performance of SiNWs by enhancing the absorption of visible light and promoting the separation of photogenerated carriers;meanwhile,CDs provide the carboxyl active site for antibody attachment.The CDs@SiNWs-based immunosensor has a good linear range(0.005-5.000 ng/mL)and a low detection limit(3.79 pg/mL)for the detection of cTnI.The designed photoelectrochemical(PEC)immunosensor has good sensitivity,stability,and reproducibility.The electrode enables label-free detection and provides a new way to achieve immediate detection of cTnI.

关键词

光电免疫传感器/心肌肌钙蛋白I/硅纳米线阵列/碳点

Key words

photoelectrochemical immunosensor/cardiac troponin I/silicon nanowire arrays/carbon dots

分类

化学化工

引用本文复制引用

黄粤夷,直士博,李慧珺..基于CDs@SiNWs的光电化学免疫传感器构建及性能研究[J].有色金属材料与工程,2024,45(3):32-37,6.

基金项目

上海市科学技术委员会项目(21ZR1444200 ()

20490761100) ()

有色金属材料与工程

2096-2983

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