有色金属材料与工程2024，Vol.45Issue(3)：55-64,10.DOI:10.13258/j.cnki.nmme.20220331002
金属-有机框架材料催化析氧反应的研究进展
Progress on metal-organic framework for oxygen evolution reaction
摘要
Abstract
With the increasing environmental crisis,the Chinese government has put forward the grand goal of"carbon neutrality,carbon peak",and clean energy is one of the effective means to achieve the double carbon goal.However,high overpotential and slow kinetics of anodic oxygen evolution reaction(OER)are the primary obstacle for improving the efficiency of water splitting to produce hydrogen by water electrolysis.Metal-organic framework(MOF)are considered as excellent catalysts for water splitting due to their regular microstructures,large specific surface area,and tunable pore size,etc.In this paper,recent research progress of MOF-based electrocatalysts for OER has been reviewed by design strategy and catalytic mechanism of MOF-based electrocatalysts.Various modulation strategies for improving the activity of MOF-based electrocatalysts,including crystallinity,electronic structure,defect and morphology,were introduced.Finally,the challenges and opportunities of MOF materials as OER catalysts are prospected.关键词
金属-有机框架/电催化/析氧反应/电解水Key words
metal-organic framework/electrocatalysis/oxygen evolution reaction/water splitting分类
信息技术与安全科学引用本文复制引用
徐静,薛裕华..金属-有机框架材料催化析氧反应的研究进展[J].有色金属材料与工程,2024,45(3):55-64,10.基金项目
国家自然科学基金资助项目(52172095) （52172095）
上海市自然科学基金资助项目(19ZR1435000) （19ZR1435000）
