磷及磷化物高压结构与性能研究进展OA北大核心

Phosphorus,a group V non-metallic element,exhibits a unique electronic struc-ture along with excellent optical,electrical and mechanical properties,and has a wide range of application prospects.Recent studies have demonstrated that phosphorus and phosphides are easily affected and regulated by external fields and have rich physical and chemical properties under high pressure.In addition,the unique structure and electronic properties of phospho-rus and phosphides give them many physical properties that differ from those of traditional materials.Therefore,the use of high pressure to induce structural transformation and super-conducting transformation in phosphorus and phosphides has become the focus of high-pressure research.In this paper,the structural,electrical,and optical responses of black phosphorus,germanium phosphide,and arsenic phosphide under high-pressure conditions are reviewed and discussed.Furthermore,we also explore the structure-activity relationships between the struc-tures and physical properties and forecast the future research directions of phosphides under high pressure.