聊城大学学报(自然科学版)2024,Vol.37Issue(4):89-102,14.DOI:10.19728/j.issn1672-6634.2023120001
多金属氧簇电催化转化研究进展
Research Progress of Polyoxometalates in Electrocatalytic Chemical Conversion
摘要
Abstract
Polyoxometalates(POMs)is a class of metal-oxygen clusters,which is composed of early tran-sition metal atoms(Mo,W,V,Nb,and Ta,etc.)and interconnected by shared oxygen atoms.POMs can be precisely controlled at the atomic level,resulting in their intriguing structures.Due to the rapid and reversible multi-electron transfer performance,POMs have drawn the widespread attention in the field of catalysis,materials science,energy,and pharmaceuticals,and become a research focus of interdisciplinary integration.In recent years,electrocatalysis has gained extensive attention because its green and clean characteristics,high atom utilization efficiency,and environmental benefits.This review provides a sum-mary of the catalytic properties and applications of POMs in the area of electrocatalytic water splitting,value-added transformation of organic molecules,and electrocatalytic CO2 conversion.In addition,the fu-ture development of POMs electrocatalysis is prospected.关键词
多金属氧簇(POMs)/电催化/CO2/产氢/有机分子转化Key words
polyoxometalates/electrocatalysis/CO2/hydrogen production/organic molecule conversion分类
化学化工引用本文复制引用
刘港,孙凤至,付仕祺,李英杰,李振,黄现强..多金属氧簇电催化转化研究进展[J].聊城大学学报(自然科学版),2024,37(4):89-102,14.基金项目
国家自然科学基金项目(21871125,22201116) (21871125,22201116)
山东省自然科学基金项目(ZR2023MB018 ()
ZR2022QB066) ()
国家大学生创新创业训练计划项目(CXCY2022026)资助 (CXCY2022026)
聊城大学大学生科技创新项目(26312170509 ()
26312170507) ()