河南科技大学学报（自然科学版）2024，Vol.45Issue(4)：88-93,6.DOI:10.15926/j.cnki.issn1672-6871.2024.04.012
碱促进碘代过氧化物的C-I键硒基化
C—I Bond Selenylation of lodoperoxides Promoted by Bases
摘要
Abstract
Taking iodine-peroxide and diphenyldiselelen ether as raw materials,dimethyl sulfoxide as solvent,ammonium iodide and potassium tert-butoxide as catalysts,C—Se bond coupling was formed at room temperature,and 11 selenium aryl peroxides were synthesized.By using HNMR spectroscopy,CNMR spectroscopy and mass spectrometry,the products were characterized and analyzed separately.Through a series of control experiments,the reaction was determined to be ionic and the corresponding reaction mechanism was inferred.The results show that 11 selenium aryl peroxides are all yellow liquid.The yield is 68％～85％.关键词
C-Se键/无金属/碱/硒芳基过氧化物Key words
C-Se bond/metal-free/base/araryl/selenoperoxide分类
化学化工引用本文复制引用
阿布力米提·阿布都卡德尔,铁星,郑凯源,再米热·罗合曼,刘昶红..碱促进碘代过氧化物的C-I键硒基化[J].河南科技大学学报（自然科学版）,2024,45(4):88-93,6.基金项目
国家自然科学基金项目(22061040) （22061040）
大学生创新项目(s202210755039) （s202210755039）
