宁夏大学学报(自然科学版)2024,Vol.45Issue(2):155-159,5.
螺[4.4]-壬烷-1,6-二酮的合成及应用研究进展
Advances in the Synthesis and Application of Spiro[4.4]-nonane-1,6-dione
摘要
Abstract
Motivated by the development of chiral ligands and catalysts,asymmetric catalytic reactions have been extensively known as one of the most efficient ways to obtain optically pure compounds.Consequently,the exploration of privileged skeletons and the development of corresponding chiral ligands and catalysts have become pivotal objectives in asymmetric catalysis research.Since the 1990s,chiral spiro-scaffolds have played a significant role in the design and synthesis of effective chiral ligands and catalysts.Among these,spiro[4.4]-nonane-1,6-dione stands out as a representative chiral spiro core structure and has been applied in the design,synthesis,and application of chiral auxiliaries,ligands,and catalysts.This paper provides a comprehensive review of the research history regarding the synthesis and applications of spiro[4.4]-nonane-1,6-dione.关键词
螺[4.4]-壬烷-1,6-二酮/螺环骨架/配体/催化剂/不对称催化Key words
spiro[4.4]-nonane-1,6-dione/spiro skeleton/ligand/catalyst/asymmetric catalysis分类
建筑与水利引用本文复制引用
李欣茹,杨彬淼..螺[4.4]-壬烷-1,6-二酮的合成及应用研究进展[J].宁夏大学学报(自然科学版),2024,45(2):155-159,5.基金项目
国家自然科学基金青年科学基金资助项目(22201205) (22201205)
兰州大学功能有机分子化学国家重点实验室开放课题基金资助项目(202328) (202328)