基于壳层法的黄陵气煤低温热解数值模拟OA北大核心CSTPCD
Numerical simulation of low-temperature pyrolysis of Huangling gas coal based on shell method
针对煤热解过程模拟难以兼顾预测能力和计算量的问题,通过壳层法与Ergun公式分别对网格单元及动量方程进行简化,同时采用水分蒸发模型、煤热解动力学模型、焦油裂解模型与控制方程结合的方法对黄陵气煤低温热解过程进行数值计算,建立了一种计算速度快且能够较好地预测煤样内部温度、气体速度、挥发分产率分布的一维瞬态模型.该模型模拟的各挥发分产率与实验结果基本吻合,误差不超过14%;低温热解模拟过程可在47 min内快速计算完成.利用该模型分析了低温热解过程中煤样内部多物理场的变化规律及其对热解进程、产物分布的影响.研究发现,水分蒸发吸热导致煤样内层升温较慢,从而迟滞热解反应的进行并增加热解反应时间;水蒸气、焦油和热解气生成速率决定气体速度,气体速度对焦油裂解反应影响显著,气体速度越小,焦油裂解越快,即从煤样外部到内部发生焦油裂解反应的概率越高;升温速率是影响热解气和焦油产率的重要因素,升温速率越低,热解越充分,挥发分所代表的热解气与焦油产率越高;煤样粒度对热解气和焦油产率的影响较小.
Aimed at solving the problem of balancing predictive accuracy and computa-tional efficiency involved in the simulation of coal pyrolysis,a one-dimensional transient model for the low-temperature pyrolysis process was established,featuring both faster computational speed and precise predictions of the internal temperature,gas velocity and volatile yield distribu-tion of coal samples.The Shell method and Ergun formula were employed to simplify the grid el-ements and momentum equation respectively.A comprehensive method integrating water evapo-ration model,coal pyrolysis kinetics model,tar pyrolysis model,and control equation was adopt-ed to numerically simulate the low-temperature pyrolysis process of Huangling gas coal.It is showed that the simulated yields of various volatile components closely aligned with the experi-mental results,with an error no more than 14%.The low-temperature pyrolysis simulation process can be completed within 47 min.This model is further used to analyze the variations of multiple physical fields within coal samples during low-temperature pyrolysis,along with their influences on the pyrolysis process and product distribution.Firstly,it is found that heat absorp-tion caused by water evaporation leads to a slower heating rate in the inner layer of coal samples,thereby delaying the pyrolysis reaction and prolonging the reaction time.Secondly,the gas veloc-ity is determined by the generation rate of water vapor,tar,and pyrolysis gas,which has a sig-nificant impact on the tar cracking reaction.A lower gas velocity facilitates faster tar cracking,increasing the probability of tar cracking reaction occurring from the outside to the inside of the coal sample.Thirdly,the heating rate is an important factor affecting the yield of pyrolysis gas and tar.The lower the heating rate,the more complete the pyrolysis,and the higher the yield of pyrolysis gas and tar.Finally,the particle size of coal samples has a relatively minor impact on the yield of pyrolysis gas and tar.
王奇;杜美利
西安科技大学化工学院,710054 西安
化学工程
黄陵气煤低温热解挥发分壳层法数值模拟
Huangling gas coallow temperature pyrolysisvolatilesshell methodnu-merical simulation
《煤炭转化》 2024 (004)
23-31 / 9
国家自然科学基金项目(41672154).
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