首页|期刊导航|首都师范大学学报(自然科学版)|全共轭二维有机框架材料在有机电子器件中的应用

全共轭二维有机框架材料在有机电子器件中的应用OACSTPCD

Application of fully conjugated two-dimensional organic frameworks in organic electronic devices

中文摘要英文摘要

有机电子器件已成为当今社会与工业中不可或缺的组成部分,在显示、通讯、能源和环境等方面都具有广泛的应用.有机电子器件的核心是有机半导体材料,开发具有高电荷传输特性的有机半导体材料是提升有机电子器件性能的关键.作为材料领域的研究前沿,有机多孔晶态材料由于具有确定的化学结构、功能可设计性、大的比表面积、高的孔隙率以及结构可修饰性等特征吸引了广泛的研究,在众多领域都展现出了广阔的应用前景.其中,由于具有高的结构平面性、电子离域性、电荷传输性质以及化学稳定性,全共轭二维有机框架材料作为有机电子学中的载流子传输材料受到广泛关注.当前,人们基于不同结构与功能的全共轭二维有机框架材料,构筑了多种有机电子器件并展现出了巨大的应用潜力.本文首先介绍目前发展的全共轭二维有机框架材料的主要结构,随后重点综述全共轭二维有机框架材料在有机电子器件包括有机场效应晶体管、有机光电探测器、有机光伏电池、化学阻抗传感器及一些新兴电子器件中的最新研究进展.最后阐述实现全共轭二维有机框架材料在有机电子器件的实际应用中所面临的挑战并提出了未来的研究方向.

Organic electronic devices have become an indispensable component in current society and industry,and have widespread applications in fields including display,communication,energy,environment and so on.Organic semiconductor materials are the core of organic electronic devices,thus developing materials with desirable charge transfer properties is the key to improving the performance of the devices.As the research frontier in material science,organic porous crystalline materials have attracted widespread research interest and shown broad application prospects in many fields due to their definite chemical structure,functional designability,large specific surface area,high porosity,and structural modifiability.Especially,fully conjugated two-dimensional(2D)organic framework materials have been studied extensively in the fields of organic electronic devices owing to their high structural planarity,strong electron delocalization,good charge transfer properties and chemical stability.Currently,various organic electronic devices have been fabricated based on fully conjugated 2D organic framework materials with different structures and functions,demonstrating their great application potentials.This review article firstly introduces the structures of developed fully conjugated 2D organic framework materials.And then the latest research progress of fully conjugated 2D organic framework materials in organic electronic devices,including organic field-effect transistors,organic photodetectors,organic photovoltaic cells,organic light-emitting diodes,chemical resistance sensors,and other emerging advanced devices,have been summarized.Finally,the challenges in realizing the practical application of fully conjugated 2D organic framework materials in the field of organic electronic devices and future research detections are also provided.

吴倩茹;王华平;付红兵

首都师范大学化学系,北京 100048

化学

全共轭二维有机框架材料有机电子器件结构与功能调控

fully conjugated 2D organic frameworksorganic electronic devicesstructural and functional regulation

《首都师范大学学报(自然科学版)》 2024 (003)

35-51 / 17

北京市自然科学基金项目(2224101);国家自然科学基金项目(22205149)

10.19789/j.1004-9398.2024.03.004

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