纤维素科学与技术2024,Vol.32Issue(2):34-39,6.DOI:10.16561/j.cnki.xws.2024.02.07
含硼/磷/氮阻燃元素的棉用阻燃剂的制备及其应用
Preparation and Application of Flame Retardants for Cotton Containing Boron/phosphorus/nitrogen Flame Retardants
摘要
Abstract
In view of the good application of phosphate flame retardants in cotton fabrics and the new era requirements for halogen-free flame retardants for scientific environmental protection,boron compounds are used as flame retardants with low toxicity and high efficiency.Therefore,a boron-phosphorus-nitrogen cross-linked flame retardant was constructed.This paper attempted to synthesize a halogen-free cotton flame retardant with a P-N-B synergistic flame retardant using inexpensive and readily available raw materials such as boric acid and hexachlorophosphazene in acetone and water system,and partially explored its properties.The results showed that when the concentration of the flame retardant was 150 g/L,the finishing liquid pH was adjusted with NH4OH,the baking temperature was 120℃,and the baking time was 6 min,the residual carbon length of the cotton fabric was 5.4 cm,and the LOI value increased to 43.5%.关键词
棉织物/阻燃性能/环保高效/协同阻燃Key words
cotton fabric/flame retardant performance/environmentally friendly and efficient/synergistic flame retardant分类
化学化工引用本文复制引用
王浩然,吕洲..含硼/磷/氮阻燃元素的棉用阻燃剂的制备及其应用[J].纤维素科学与技术,2024,32(2):34-39,6.基金项目
国家自然科学基金(22075158). (22075158)