广东石油化工学院学报2024，Vol.34Issue(3)：8-13,6.
新型铁合物的合成、晶体结构以及Hirshfeld表面分析
Synthesis,Crystal Structure,and Hirshfeld Surface Analysis of Novel Iron Metal Complexes
摘要
Abstract
Two novel iron complexes[Fe2(L1')2(DMSO)2]·2DMSO·C4H10S2(1)(H3L1'=(E)-2,4-dichloro-6-((4-((3,5-dichloro-2-hydroxybenzylidene)amino)-4H-1,2,4-triazol-3-yl)(hydroxy)methyl)phenol,DMSO=dimethyl sulfoxide,C4H10S2=1,3-dimethyl-1λ4,3λ4-dithiabicyclo[1.1.0]butane)and[Fe2(L2')2(DMSO)2]·2DMSO·C4H10S2(2)(H3L2'=(E)-2,4-dibromo-6-((4-((3,5-dibromo-2-hydroxybenzylidene)amino)-4H-1,2,4-triazol-3-yl)(hydro-xy)methyl)phenol)were synthesized by solvothermal method.Complexes 1 and Complexes 2 have similar structures and belong to the triclinic crystal system with Pī space group.The molecular structure of the complexes contains two Fe ions,two ligand molecules,two DMSO molecules and two free solvent molecules.Both iron ions are six-coordinated octahedral FeNO5 configuration.The interaction forces between the complexes were analyzed by the Hirshfeld surface analysis diagram and two-dimensional fingerprinting.关键词
席夫碱/金属配合物/晶体结构/Hirshfeld表面分析Key words
Schiff base/metal complexes/crystal structure/Hirshfeld surface analysis分类
数理科学引用本文复制引用
柯志林,付春晓,范艺蓝,张淑华..新型铁合物的合成、晶体结构以及Hirshfeld表面分析[J].广东石油化工学院学报,2024,34(3):8-13,6.基金项目
国家自然科学基金项目(21861014) （21861014）
广东石油化工学院高层次人才项目(2020RC033) （2020RC033）
