宁夏工程技术2024，Vol.23Issue(2)：115-123,131,10.
有机铝催化的不饱和化合物硼氢化反应
Hydroboration of Unsaturated Substrates Catalyzed by Organoaluminum
摘要
Abstract
Green,eco-friendly and atomic economy has become a hot topic in chemical research,and the development of inexpensive,high quality,green,eco-friendly and atomic economy catalysts is one of challenges that chemists need to break through in the present and future.The transition metal complexes are highly favored because of the excellent redox ability of the center metal,and have been widely used as catalysts in the organic reactions.Compared with transition metal complexes,the main group metal catalysts are considered as new catalysts with wide commercial applications and environmental friendliness.With the continuous development and research of main group organometallics(especially the low valence organometallics),the catalytic properties and applications of main group organometallics have attracted wide attention.In recently,with the pioneering discovery of β-diimide aluminum dihydrogen catalytic performance,the research on exploring green organoaluminum catalysts has been developed rapidly.In this paper,the hydroboration of unsaturated compounds catalyzed by organoaluminum is reviewed,and its catalytic mechanism and reaction process are systematically summarized.The analysis and prospect of organoaluminum catalysts are also presented,in order to provide material for the development of main group element organic catalysts and the study of their catalytic mechanism.关键词
有机铝/不饱和化合物/硼氢化反应/绿色催化剂/催化机理Key words
organoaluminum/unsaturated substrate/hydroboration/green catalyst/catalytic mechanism引用本文复制引用
马应花,刘鑫,冯雪兰,郭燕,刘翔宇,丁毅..有机铝催化的不饱和化合物硼氢化反应[J].宁夏工程技术,2024,23(2):115-123,131,10.基金项目
宁夏回族自治区教育厅高等学校科学研究项目(NYG2022024) （NYG2022024）
宁夏自然科学基金项目(2023AAC03008 （）
2022AAC03041) （）
