重庆大学学报2024，Vol.47Issue(6)：35-42,8.DOI:10.11835/j.issn.1000-582X.2023.264
碳化对含花岗岩石粉硫氧镁水泥的抗压强度和耐水性的影响
Effect of carbonation on the properties of granite-bearing oxysulfate oxide cement
摘要
Abstract
The properties of magnesium oxysulfate (MOS) cement with different granite powder (GP) contents with CO2 curing were studied. The hydration products and microstructure of MOS cement were analyzed using X-ray diffraction (XRD),simultaneous comprehensive thermal analyzer (TG-DSC),scanning electron microscope (SEM) and mercury porosimeter (MIP). The results shows that the strength retention coefficient of MOS cement containing 40％ GP reached 1.12 with standard curing for 28 days followed by 28 days of CO2 curing;when MOS cement was CO2-cured for 28 days and then immersed in water for 120 days,the strength retention coefficient reached 0.94,which was 123.8％ higher than that of blank samples. MgCO3·zH2O crystals were generated after MOS cement underwent CO2 curing,which had a positive effect on the mechanical properties and water resistance by reducing matrix expansion caused by MgO hydrating to Mg(OH)2. GP increased the matrix density,reduced the CO2 capture rate,and decreased CO2 erosion of MOS cement by optimizing the pore structure. The presence of GP and magnesium carbonate phases improved the compressive strength of MOS cement after carbonation and immersion.关键词
硫氧镁水泥/碳化/耐水性/碳酸镁Key words
magnesium oxysulfate cement/carbonation/water resistance/magnesium carbonate分类
建筑与水利引用本文复制引用
靳凯戎,张晓静,毕万利,王德志,韩静云..碳化对含花岗岩石粉硫氧镁水泥的抗压强度和耐水性的影响[J].重庆大学学报,2024,47(6):35-42,8.基金项目
国家自然科学基金资助项目(51968060,52368037) （51968060,52368037）
宁夏青年拔尖人才培养工程(2080116) （2080116）
宁夏重点研发计划项目(2022BEE03001) （2022BEE03001）
宁夏一流学科项目(NXYLXK2021A03) （NXYLXK2021A03）
宁夏自然科学基金(2023AAC03040).Supported by National Natural Science Foundation of China(51968060,52368037),the Ningxia Youth Talent Support Program(2080116),the Key Research and Development Program of Ningxia Province(2022BEE03001),Ningxia First Class Discipline Project(NXYLXK2021A03),and the National Natural Science Foundation of Ningxia(2023AAC03040). （2023AAC03040）
