大学化学2024，Vol.39Issue(6)：390-399,10.DOI:10.3866/PKU.DXHX202403028
有机-无机杂化材料动力学与热力学转化以及荧光信息防伪应用研究
Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information:Introducing a Comprehensive Chemistry Experiment
摘要
Abstract
Organic-inorganic hybrid luminescent materials are highly favored in the luminescence anti-counterfeiting field due to their tunable structural and luminescent properties. This study investigates Sb(Ⅲ) doped Bi(Ⅲ)-based zero-dimensional organic-inorganic hybrid metal halides,demonstrating the transformation from kinetic products (compound 1) to thermodynamic products (compound 2) by various crystal growth methods. X-ray powder diffraction and fluorescence spectroscopy were employed to characterize their phase and optical properties,revealing distinct differences between the two compounds. Compound 2 exhibits fluorescence quenching when exposed to distilled water and possesses robust hydrophobic properties,allowing for stable long-term storage in aqueous environments. Leveraging the exceptional color-changing properties of compound 2,a simple water-writable fluorescent anti-counterfeiting board/paper was fabricated. This experiment exemplifies the principle that "structure determines properties" and embodies the educational philosophy of "learning through application". The experimental design and implementation aim to cultivate students' innovative thinking and enhance their abilities to analyze and solve practical issues.关键词
Sb(Ⅲ)掺杂Bi(Ⅲ)基杂卤化物/光致发光/动力学与热力学转化/水致变色/可写荧光防伪应用Key words
Sb(Ⅲ) doped Bi(Ⅲ)-based hybrid halides/Photoluminescence/Kinetic and thermodynamic conversion/Water-induced chromism/Writable fluorescent anti-counterfeiting application分类
社会科学引用本文复制引用
吴越,李钧,张波,杨燕,李海波,张宪玺..有机-无机杂化材料动力学与热力学转化以及荧光信息防伪应用研究[J].大学化学,2024,39(6):390-399,10.基金项目
省级大学生创新创业训练计划项目(S202310447076) （S202310447076）
山东化学教指委教学改革研究项目(SDHX-YB-2022-22,SDHX-ZD-2022-12) （SDHX-YB-2022-22,SDHX-ZD-2022-12）
聊城大学教学研究重点资助项目(G2022004) （G2022004）
聊城大学实验教学改革项目(26322170106,26322170212) （26322170106,26322170212）
