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铁铝酸盐、硫铝酸盐和硅酸盐水泥的水化进程对比研究

李红轩 齐冬有 邹德麟 王剑锋 汪智勇 郝禄禄 王亚丽 张钰 刘洪印

硅酸盐通报2024,Vol.43Issue(7):2335-2345,11.
硅酸盐通报2024,Vol.43Issue(7):2335-2345,11.

铁铝酸盐、硫铝酸盐和硅酸盐水泥的水化进程对比研究

Comparative Study on Hydration Process of Ferroaluminate,Sulfoaluminate and Portland Cement

李红轩 1齐冬有 2邹德麟 3王剑锋 1汪智勇 2郝禄禄 3王亚丽 1张钰 2刘洪印3

作者信息

  • 1. 北京工业大学材料科学与工程学院,北京 100124
  • 2. 建筑材料工业技术监督研究中心,北京 100124
  • 3. 中核国电漳州能源有限公司,漳州 363300
  • 折叠

摘要

Abstract

Ferroaluminate cement has the characteristics of energy conservation,waste utilization,emission reduction,excellent process performance and environmental friendliness,and has gradually attracted the research interest of scholars at home and abroad.This article compared the hydration processes of three different cement systems,namely ferroaluminate cement(FAC),sulfoaluminate cement(SAC),and Portland cement(PC),through test methods such as hydration heat,XRD,TG-DTG,pore structure analysis,and SEM.The hydration products and mechanisms of three types of cement were analyzed.The results show that the 1 d strength of FAC increases by 130%compared to PC,and the 28 d strength exceedes SAC.The hydration heat release of FAC and SAC is mainly concentrated within 1 d,and the iron phase in FAC clinker can shorten the acceleration period and promote the formation of ettringite.Compared with PC and SAC,FAC hydration products contain not only ettringite,hydrated calcium silicate gel and aluminum glue,but also ettringite and iron glue,with lower total porosity,more compact structure of cement stone,and further improved strength and durability.

关键词

硅酸盐水泥/硫铝酸盐水泥/铁铝酸盐水泥/水化进程/水化产物/微观分析

Key words

Portland cement/sulfoaluminate cement/ferroaluminate cement/hydration kinetic/hydration product/microscopic analysis

分类

化学化工

引用本文复制引用

李红轩,齐冬有,邹德麟,王剑锋,汪智勇,郝禄禄,王亚丽,张钰,刘洪印..铁铝酸盐、硫铝酸盐和硅酸盐水泥的水化进程对比研究[J].硅酸盐通报,2024,43(7):2335-2345,11.

基金项目

北京市科技计划项目(Z221100007522002) (Z221100007522002)

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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